The organosilicon pyridine-2-olates 1a–1d (RSi(pyO)3, R = Me (a), Ph (b), Bn (c), Allyl (d); pyO pyridine-2-olate) may serve as tripodal ligands toward CuCl with formation of complexes the type RSi(?2-pyO)3CuCl (2a–2d). In addition, for Allyl, more stable isomer 2d? (?O-pyO)Si(?2-pyO)2(?2-Allyl)CuCl was observed. presence dry air (as a source oxygen), reactions and afforded Cu(II) RSi(?2-pyO)4C...