Energy-efficient photocatalytic CO2 reduction (PCO2R) into sustainable solar fuels is a highly enticing challenge for simultaneous settling of energy and environmental issues. Herein, we illustrate the synthesis performance judiciously designed plasmonic Au nanoparticles photodeposited on TiO2-decorated N-doped graphene (ANGT-x) heterostructure catalyst showing remarkably enhanced activity with...

Ag core–TiO2 shell (Ag@TiO2) structured nanoparticles with Ag to TiO2 molar ratio of 1:1.7 were synthesized using one pot synthesis method and post calcination was carried out at 450 C for 3 h to convert it from amorphous to crystalline form. The Ag core and TiO2 shell formation was confirmed by TEM and AFM. The particle size analysis revealed the average size of Ag@TiO2 as approximately around...

In this paper, a Cu, N co-doped TiO2 nanosheet with increased visible light photocatalytic activity was successfully synthesized using a biomimetic layer-by-layer deposition process. The polymer, branched-polyethyleneimine (b-PEI) was used as an induction agent for the hydrolysis of titanium bis(ammonium lactato)-dihydroxide (Ti-BALDH) as well as for a nitrogen resource, and the graphene oxide ...

Boron doped graphene nanosheets (B-GR) as a p-type semiconductor, provides much more edges to facilitate the loading of TiO2 nanoparticles (P25). Highly-dispersed P25/B-GR nanosheets with the size of 20-50 nm, are successfully synthesized by the vacuum activation and ultraphonic method. The nanosized morphology can decrease the local density of defects which are induced by the boron substitutio...

Abstract The band-gap energy of TiO2 nanoparticles has been modified using different methods. study reviewed the effects doping and co-doing nanotubes with metals nonmetals to modify its band gap improves photocatalytic activity nanoparticles. From our findings reviewing articles, dissimilar metal ions like Cerium (Ce) together nitrogen (N) or chromium (Cr) iron (Fe) will decrease particle size...

We studied the electronic and atomic structures of anatase TiO2 codoped with Cr and N using hybrid density functional theory calculations. The nonlocal screened Hartree-Fock exchange energy is partially mixed with the traditional semilocal exchange energy. This not only patches the bandgap underestimation but also improves the description of the anion/cation-driven impurity states and the magne...

Hetero-element doping (e.g., N, F, C) of TiO2 is inevitably accompanied by significantly increased structural defects due to the dopants' nature being foreign impurities. Very recently, in situ self-doping with homo-species (e.g., Ti(3+)) has been emerging as a rational solution to enhance TiO2 photoactivity within both UV and visible light regions. Herein we demonstrate that conventional elect...

The spin or nonspin state of electrons in W-doped anatase TiO2 is very difficult to judge experimentally because of characterization method limitations. Hence, the effect on the microscopic mechanism underlying the visible-light effect of W-doped anatase TiO2 through the consideration of electronic spin or no-spin states is still unknown. To solve this problem, we establish supercell models of ...

Micropollutants (MPs) are widely occurring in surface water all over the world with extremely low concentrations, and their treatment requires high energy consumption efficiency. In this study, a large-sized planar photocatalytic reactive ceramic membrane (PRCM) was prepared using facile dip-coating method nitrogen-doped TiO2 (N-TiO2-CM) for purification of tetracycline hydrochloride (TC) as mo...

PURPOSE This laboratory study aimed to investigate the effect of doping an acrylic denture base resin material with nanoparticles of ZnO, CaO, and TiO2 on biofilm formation. MATERIALS AND METHODS Standardized specimens of a commercially available cold-curing acrylic denture base resin material were doped with 0.1, 0.2, 0.4, or 0.8 wt% commercially available ZnO, CaO, and TiO2 nanopowder. Ener...