We present the first polymorph interconversion study that uses solid-state dynamic covalent chemistry (DCC). This system exhibits unexpected and rich behavior, including the observation that under appropriate conditions the polymorph interconversion of a heterodimer proceeds through reversible covalent chemistry intermediates, and this route is facilitated by one of the two disulfide homodimers...

Nanocrystalline soft magnetic alloys can be produced by partial crystallization of amorphous precursor. The aim of this paper was to study the influence of Nb substitution by vanadium (V) in Fe73.5Cu1Nb3-xVxB9Si13.5 (x=1.5, 3) alloys on their crystallization process and the glass forming ability because the growth of the α-Fe(Si) crystals is reduced by (Nb) diffusion barrier. Amorphous ribbons ...

Light-to-electricity conversion efficiency in dye-sensitized solar cells critically depends not only on the dye molecule, semiconducting material and redox shuttle selection but also on the particle size and particle size distribution of the semiconducting photoanode. In this study, nanocrystalline BaSnO3 and SrSnO3 particles have been synthesized using the microemulsion method. Particle size d...

Nanocrystalline ZnO photocatalysts were prepared by a sol-gel method and modified with fluorine to improve their photocatalytic anti-bacterial activity in visible light. Pathogenic bacteria such as Escherichia coli (Gram-negative) and Staphylococcus aureus (Gram-positive) were employed to evaluate the antimicrobial properties of synthesized materials. The interaction with biological systems was...

nanocrystalline complex oxides have been synthesized by combination of sol–gel auto combustion and ultrasonic irradiation techniques using copper nitrate, zinc nitrate as metallic nitrates and glycine, urea and thiourea as fuels. sol-gel combustion (combination of the chemical sol–gel process and the combustion process) as a proper synthesized technique is used to synthesize zno/cuo nanocomposi...

In the present study, structural characterization of NiTi smart shape memory alloys (SMAs), produced by an alternative powder metallurgy approach named mechanically activated reactive forging (MARFOS), was carried out by means of transmission electron microscopy (TEM), scanning electron microscopy (SEM) and X-ray diffraction (XRD). It was observed that MARFOS materials had a multiphase nanocrys...

A method towards the solution and refinement of organic crystal structures by fitting to the atomic pair distribution function (PDF) is developed. Approximate lattice parameters and molecular geometry must be given as input. The molecule is generally treated as a rigid body. The positions and orientations of the molecules inside the unit cell are optimized starting from random values. The PDF i...