The solubility of NiO(cr) was measured using flow techniques and a potentiometric method from ca. 0 to 350°C in aqueous solutions as a function of pH. A more limited study of the solubility of -Ni(OH)2(cr) was conducted by both techniques to 200°C. These results indicate that the transition temperature at which nickel hydroxide dehydrates to form the oxide is ca. 75°C, much lower than previousl...

The catalyst formation in the system Ni(acac),, C&I,, (iBu)sAl was investigated by means of infrared spectroscopy. It was found that the Al(acac)s and (iBu)&l(acac) formed are both by-products of catalyst formation without a catalytic activity. Ni(acac)z loses its acac groups forming the unstable (iBu)sNi compound; without CsH, being present, this compound disproportionates to Ni metal and isob...

We design a novel nano-gap electrode to measure the current of DNA molecule, by which the current-voltage characteristics of individual native DNA, Ag-DNA and Ni-DNA molecules are obtained, respectively. The results show that the voltage gap of Ag- and Ni-DNA is higher than that of native DNA, and the conductance is lower than native DNA in neutral environment. The structure transition from B- ...

In the past 30 years, electroless nickel (EN) plating has grown to such proportions that these coatings and their applications are now found underground, in outer space, and in a myriad of areas in between. Moreover, in order to further improve the mechanical and tribological properties of the nickel-phosphorous (Ni-P) coatings, Ni-P/PTFE composite coatings can be obtained, which provides even ...

Electrospray ionization (ESI) of methanolic solutions of monomeric nickel(II) acetate, [Ni(CH(3)COO)(2)], and tetrameric platinum(II) acetate, [Pt(4)(CH(3)COO)(8)], leads to the formation of the corresponding methylidyne complexes [M(CH)](+) (M = Ni, Pt), which react with ammonia under C-N coupling. While the product couples M/[CH(4)N](+) and [M(CH(2)N)](+)/H(2) are observed for both metals, hy...

Bacteria require nickel transporters for the synthesis of Ni-containing metalloenzymes in natural, low nickel habitats. In this work we carry out functional and topological characterization of Rhizobium leguminosarum HupE, a nickel permease required for the provision of this element for [NiFe] hydrogenase synthesis. Expression studies in the Escherichia coli nikABCDE mutant strain HYD723 reveal...

This study was carried out to add scientific data in regard to the use of metallic nanoparticles in nanomedicine. The acute toxicity of nickel (Ni) nanoparticles (50 nm), intravenously injected through the dorsal penile vein of Sprague Dawley rats was evaluated in this study. Fourteen days after injection, Ni nanoparticles induced liver and spleen injury, lung inflammation, and caused cardiac t...

to evaluate the effect of application of municipal solid waste compost (mswc) on the accumulation of heavy metals of lead, nickel and cadmium in the soil under maize cultivation, a factorial experiment in base randomized complete block design (rcbd) with four different amounts of municipal solid waste compost (zero, 15, 30 and 60 tons ha-1) and time (compost applied once or twice) was performed...

To improve the electromagnetic characteristics of conductive nano fillers, carbon nanofibers (CNFs) with nickel-phosphorous (Ni-P) and nickeliron (Ni-Fe) have been fabricated by the electroless plating process. Observations by the electron microscopy (SEM/TEM) and element analyzer (EDS/ELLS) showed the uniform Ni-P and Ni-Fe coated CNFs. The compositions of the plating layers were about Ni-6wt%...

in the recent years, agricultural soils have received more chemicals in various forms for higher yields. this may result in the accumulation of metals in soils which subsequently may be transferred into the agricultural crops. in the present investigation, nickel content of 58 composite soil samples and also agricultural crops, is studied. ni in samples of soil and agricultural products were ex...