We have applied the method to carbon formation in C02 reforming of methane over eight transition metals, starting with a list of 164 elementary steps and published UBI-QEP calculations of their activation energies and using the MECHEM program for combinatorial pathway generation. The predicted coking pattern Fe > Ni > Ru > Rh, Ir, Pd > Cu, Pt is consistent with experimental results from the lit...

b Catalytic steam reforming of methane, methanol, and ethanol over Ni/YSZ: The possible use of these fuels in internal reforming SOFC N. Laosiripojana a,∗, S. Assabumrungrat b a The Joint Graduate School of Energy and Environment, King Mongkut’s University of Technology Thonburi, Bangkok 10140, Thailand b Center of Excellence on Catalysis and Catalytic Reaction Engineering, Department of Chemic...

Decreasing supplies of high quality crude oil and increasing demand for high quality distillates have motivated the interest in converting natural gas to liquid fuels, especially with the present boom in natural gas proven reserves. Nevertheless, one major issue is the curtailment of costs incurred in producing synthesis gas from natural gas, which account for approximately 60% of the costs use...

In this work, an experimental study of biomass gasification in different operation conditions has been carried out in an updraft gasifier combined with a porous ceramic reformer. The effects of gasifier temperature, steam to biomass ratio (S/B), and reforming temperature on the gas characteristic parameters were investigated with and without porous ceramic filled in reformer. The results indica...

Future large-scale production of H2 for use as a clean fuel will likely depend upon gasifying coal or biomass followed by steam reforming the resulting gas mixture and separating the CO2 byproduct. The process of steam reforming and CO2 separation can be greatly simplified by utilizing a new material that combines a reforming catalyst with a sorbent for CO2. Such a material was prepared in the ...

Two power plant schemes that reduce CO2 emission and employ natural gas reforming were analyzed and discussed. The first one integrates natural gas reforming technology for efficiency improvement with an oxy-fuel combined power system (OXYF-REF), with water as the main work fluid. The reforming heat is obtained from the available turbine exhaust heat, and the produced syngas is used as fuel wit...

The intrinsic kinetics and diffusion behaviour of methane steam reforming have been investigated in this work. Measurements of effective diffusivities of the gases present in methane steam reforming have been carried out by using the steady-state technique over wide ranges of temperature and pressure in a modified Wicke-Kallenbach (W-K) type diffusion apparatus. The effects of diffusion limitat...

Hydrogen demand in refineries is increasing vigorously due to the stringent transportation fuel specifications, furthermore the interest in the so-called hydrogen economy developed in the recent years put the hydrogen as energy carrier in the centre of a growing interest. More than 95% of the hydrogen for refinery use is nowadays produced via hydrocarbon steam reforming, where Foster Wheeler pl...

Photocatalytic water splitting and organic reforming based on nano-sized composites are gaining increasing interest due to the possibility of generating hydrogen by employing solar energy with low environmental impact. Although great efforts in developing materials ensuring high specific photoactivity have been recently recorded in the literature survey, the solar-to-hydrogen energy conversion ...