conclusions changes of ph could remarkably affect the efficiency and oxidation rate of mtbe. in particular, the amount of kap in terms of oxidation declines substantially by moving away from the optimum ph range. in this study, ph 3.5 was considered as the optimal ph in h2o2/nzvi/ultrasonic oxidation process, with the elimination of about 89.56% of the high mtbe concentration. in general, we ca...

This work aims at investigating the kinetic mechanisms of reduction/oxidation (redox) reactions iron oxide/iron pellets under different operating conditions. The reaction principle is basis a thermochemical hydrogen storage system. To simulate charging phase, single pellet consisting oxide (90% Fe2O3, 10% stabilising cement) reduced with (H2) concentrations temperatures between 600 and 800 °C. ...

NADH:ubiquinone oxidoreductase (complex I) from bovine heart mitochondria is a complicated, energy-transducing, membrane-bound enzyme that contains 45 different subunits, a non-covalently bound flavin mononucleotide, and eight iron-sulfur clusters. The mechanisms of NADH oxidation and intramolecular electron transfer by complex I are gradually being defined, but the mechanism linking ubiquinone...

Abstract Surfactant‐free one‐step redox reactions between two types of metal cations enable the synthesis core‐shell nanoparticles without sophisticated control. The reduced noble form a solid core, and transition dissolved upon oxidation induce subsequent formation oxide shell. Various nanostructures are obtained from combination reduction‐preferring Au 3+ , Pd 2+ Pt Rh Ir cations, oxidation‐p...

Chemical reactions pertinent to karst systems divide broadly into (a) speciation reactions within aqueous solutions, (b) dissolution/precipitation and other acid/base reactions between aqueous solutions and solid minerals, and (c) redox reactions involving various carbon and sulfur-bearing species. As a backdrop against which other chemistry can be evaluated, selected phase diagrams and equilib...

riboflavin and protoporphyrin ix are two molecules that participate in oxidation and reduction reactions in the living cell. changing some functional groups of riboflavin and protoporphyrin ix can provide compounds with self-assembled monolayer properties with wide applications in designing the molecular electronic devices. in this study, the amphiphilic structure of riboflavin and protoporphyr...

Cytochrome b(5) is a microsomal protein that functions as an intermediate electron donor in fatty acid desaturation and other oxidation/reduction reactions. cDNA clones were isolated from cauliflower (Brassica oleracea L.) by using oligonucleotides based on the partial amino acid sequence of the protein. The deduced amino acid sequence of the polypeptide exhibited approximately 30% sequence ide...

Tunable surface: The surface structure of the Fe-Pt bimetallic catalyst can be reversibly modulated between the iron-oxide-rich Pt surface and the Pt-skin structure with subsurface Fe via alternating reduction and oxidation treatments (see figure). The regenerated active Pt-skin structure is active in reactions involving CO and/or O.

Under anaerobic conditions, in the dark and in the absence of electron acceptors, organic compounds are catabolized by strictly anaerobic or facultatively anaerobic bacteria by internally balanced oxidation–reduction reactions, a process called fermentation. In fermentation, the organic compound serves as both electron donor and acceptor, and adenosine triphosphate is synthesized by substrate l...

Corrosion is explained as metal or alloy changes by chemical or electrochemical process or physical changes because of environmental effects. Corrosion occurs with oxidation and reduction reactions. In this study, Some general informations were given in the introduction section. And then, monomer synthesis, conducting polymers, nanocomposites, copolymers, and applications of corrosion protectio...