ABSTRACT. A novel distorted square-planar palladium(II) complex of the type [Pd(Hdz)(PPh3)Cl], where (Hdz = dithizone mono deprotonate and PPh3 triphenylphosphine), was synthesized in dichloromethane reactions between PdCl2 a mixture Hdz PPh3. The new Pd(II) has been identified by FT-IR, electronic spectra, DFT calculations, molar conductivity, single-crystal X-ray diffraction. An diffraction s...

The selective metallization of nonconductive polymer materials has broad applications in the fields integrated circuit technology and metallized patterns. This work discusses a methodology to pattern metal tracks on polybutylene terephthalate substrates. process consists three steps: 1) surface patterning with picosecond laser pulses (1030 nm) air, 2) Pd seeding via treatment PdCl2 solution, 3)...

The reductive cyclization of suitably substituted organic nitro compounds by carbon monoxide is a very appealing technique for the synthesis heterocycles because its atom efficiency and easiness separation only stoichiometric byproduct CO2, but need pressurized CO has hampered diffusion. We have recently reported on indoles o-nitrostyrenes using phenyl formate as surrogate, palladium/1,10-phena...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

Thanks to the +PCy3 substituents which are unlikely undergo intramolecular C–H activation, Pd(II) complex [(C,C,C)PdCl](OTf) having a neutral LX2-type NHC, diphosphonium bis(ylide) pincer ligand was selectively prepared by double deprotonation of [(NHC)PdCl2(Py)] precursor with tBuOK. The influence on overall electronic properties this scaffold evaluated IR spectroscopy data corresponding Pd–CO...