The trans-dihydrodiols produced during the metabolism of phenanthrene by Cunninghamella elegans, Syncephalastrum racemosum, and Phanerochaete chrysosporium were purified by high-performance liquid chromatography (HPLC). The enantiomeric compositions and optical purities of the trans-dihydrodiols were determined to compare interspecific differences in the regio- and stereoselectivity of the fung...

In the title compound, C37H21ClO3, the dihedral angle between the two phenanthrene moieties is 57.79 (5)°. The furan and one of the phenanthrene groups are fused in an almost coplanar arrangement [dihedral angle = 5.14 (8)°] and the furan unit makes dihedral angles of 70.27 (11) and 57.58 (8)° with the planes of the phenyl and the second phenanthrene group, respectively. In the crystal, neighbo...

Polycyclic aromatic hydrocarbons (PAHs) are believed to be among the causative agents for lung cancer in smokers. PAHs require metabolic activation for carcinogenicity. One pathway produces diol epoxides that react with DNA, causing mutations. Because diol epoxides are converted to tetraols, quantitation of tetraols can potentially be used to identify smokers who may be at higher risk for lung ...

viable cell concentration and luminescence activity of p. stutzeri p16 luxab4 was measured byplate counting and luminometery in sterile and non-sterile soil adjusted to matric potential of -1500, -750 and-30 kpa. results showed that matric potential had a significant effect on survival and activity of p. stutzerip16 luxab4 in soil. p. stutzeri p16 luxab4 could survive better in hutner’s minimal...

Polycyclic aromatic hydrocarbons (PAH) are toxic, mutagenic, and carcinogenic compounds. Removal of these compounds has a great importance for environment. Removal of PAHs from soil is difficult as these chemicals are persistent in the soil. In this research, bioremediation of soil contaminated by (PAH) using Bacillus subtilis DSMZ 3256 (B.subtilis) strains was studied. The effect of electrokin...

Polycyclic aromatic hydrocarbons (PAHs) are strong toxic compounds mainly released to the environment during combustion of fossil fuels, and have effects on living organisms, with soil being one their main reservoirs. High PAH levels in soils can interfere plant growth biomass production, causing several losses diversity. In this study, we evaluated co-inoculation Trichoderma viride Funneliform...

A biosensor for detecting the toxicity of polycylic aromatic hydrocarbons (PAHs) contaminated soil has been successfully constructed using an immobilized recombinant bioluminescent bacterium, GC2 (lac::luxCDABE), which constitutively produces bioluminescence. The biosurfactant, rhamnolipids, was used to extract a model PAH, phenanthrene, and was found to enhance the bioavailability of phenanthr...

The accumulation kinetics of the amphipod Diporeia sp. for sediment-sorbed polycyclic aromatic hydrocarbon (PAH) congeners were measured where the contact time between the PAH congeners and the sediments varied between 3 and 150 d. Diporeia were exposed to a reference sediment dosed with two radiolabeled PAHs (phenanthrene and pyrene) and to sediments dosed with the two radiotracers and a mixtu...

The effect of pH, ionic strength, and cation in solution on the binding of phenanthrene by a soil humic acid in the aqueous phase was determined using fluorescence quenching. The phenanthrene binding coefficient with the dissolved soil humic, Koc, decreased with increasing ionic strength and solution cation valence. At low values of ionic strength, Koc values for this soil humic acid increased ...