نتایج جستجو برای: piperidines

تعداد نتایج: 269  

2010
Francesco Berardi Carmen Abate Savina Ferorelli Vincenzo Uricchio Nicola A. Colabufo Mauro Niso Roberto Perrone

σ2-Agonist 1-cyclohexyl-4-[3-(5-methoxy-1,2,3,4-tetrahydronaphthalen-1-yl)propyl]piperazine (7, PB 28), which proved to revert doxorubicin resistance in breast cancer cells, was taken as a template to prepare new analogs. One of the two basic N-atoms was alternatively replaced by amethine or converted into an amide or ammonium function, with the aim of finding out which of themwas essential for...

Journal: :Angewandte Chemie 2004
Frank Glorius Nick Spielkamp Sigrid Holle Richard Goddard Christian W Lehmann

available and the reaction has the potential for the simultaneous creation of multiple stereocenters. Here we describe an efficient and unprecedented auxiliary-based method for the asymmetric hydrogenation of substituted pyridines (YR= N), which enables the stereoselective formation of piperidines with up to four new chiral centers in a single operation (Scheme 2a). The heterogeneous catalytic ...

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