The cationic charged chitosan and the weak polyacid poly(ethylene-alt-maleic acid) are used to build polyelectrolyte multilayers (PEMs). To study rotational dynamics of polymer backbone in swollen state PEMs using electron paramagnetic resonance spectroscopy, a nitroxide spin-label is covalently attached polyacid. It found that spectra with even number layers show superposition two spectral com...