Monodispersed quantum dots (QDs)-encoded polymer microbeads were generated using a simple capillary fluidic device (CFD). The polymer and QDs solution was emulsified into monodispersed microdroplets by the CFD and obtained droplets were solidified via solvent evaporation. Polymer microbeads can be fabricated in a range of different sizes through changing the flow rates of the two immiscible pha...

Two cadmium-based nanocrystals were studied, cadmium selenide and cadmium telluride, which have potential applications in optoelectronic devices. CdSe quantum dots and nanorods were synthesized with a functional ligand, allowing for the formation of nanocomposites where a vinyl terminated conjugated polymer is attached through a mild Heck coupling. This provided a direct connection between the ...

This study aims to modify a cyclodextrin-PEI-based polymer, PEI-β-CyD, with the TAT peptide for plasmid DNA delivery to placenta mesenchymal stem cells (PMSCs). By using the disulfide exchange between the SPDP-activated PEI-β-CyD and TAT peptide, the TAT-PEI-β-CyD polymer was fabricated and the success of this was confirmed by the presence of characteristic peaks for PEI (at δ 2.8-3.2 ppm), CyD...

The majority of anticancer drugs have poor aqueous solubility, produce adverse effects in healthy tissue, and thus impose major limitations on both clinical efficacy and therapeutic safety of cancer chemotherapy. To help circumvent problems associated with solubility, most cancer drugs are now formulated with co-solubilizers. However, these agents often also introduce severe side effects, there...

We report a general method for the solid-phase synthesis of polymers via the ring-opening metathesis polymerization (ROMP). The method involves polymerization in solution to form a block copolymer, immobilization of the polymer via reaction of one block with a resin-bound functional group, modification of the other block, and liberation of the polymer from the resin. We demonstrated the utility...

Donor-acceptor polymers with an alternating array of donor and acceptor moieties have gained particular attention during recent years as active components of organic electronics. By implementation of suitable subunits within the conjugated backbone, these polymers can be made either electron-deficient or -rich. Additionally, their band gap and light absorption can be precisely tuned for improve...

Boron nitride nanotubes (BNNTs) are functionalized and solubilized in organic solvents such as chloroform, methylene chloride, and tetrahydrofuran by using conjugated poly(p-phenylene ethynylene)s (PPEs) (polymers A and B) and polythiophene (polymer C) via a noncovalent functionalization approach through strong π-π stacking interactions between the conjugated polymers and BNNTs. The functionali...

We have measured the ratio, r 1⁄4 sS=sT of the formation cross section, of singlet (S) and triplet (T) excitons from polarons in p-conjugated oligomer and polymer films, using a spectroscopic/magnetic resonance technique. We show that exciton formation from separated polaron pairs in p-conjugated compounds is spin-dependent, specifically r > 1: Moreover, we discovered a universal relation betwe...

We have investigated the photophysics of the luminescent polymer poly~1,3-phenylenevinylene-alt-2,5dioctyloxy-1,4-phenylenevinylene! by a variety of optical spectroscopies. The incorporation of alternating meta-phenylene and para-phenylene rings restricts conjugation with respect to poly~para-phenylenevinylene! derivatives. As a consequence, excited states are blueshifted and the nonlinear susc...