We have established methods to evaluate key properties that are needed to commercialize polyelectrolyte membranes for fuel cell electric vehicles such as water diffusion, gas permeability, and mechanical strength. These methods are based on coarse-graining models. For calculating water diffusion and gas permeability through the membranes, the dissipative particle dynamics–Monte Carlo approach w...

Real-time diagnosis is required to ensure the safety, reliability, and durability of polymer electrolyte membrane fuel cell (PEMFC) system. Two categories methods are (1) intrusive, time consuming, or require alterations architecture but provide detailed information about system (2) rapid benign low-information-yielding. A strategy based on alternating current (AC) voltage response one-dimensio...

Polymer electrolyte membranes (PEM) and Pt-based catalysts are two crucial components which determine the properties and price of fuel cells. Even though, PEM faces problem of fuel crossover in liquid fuel cells such as direct methanol fuel cell (DMFC) and direct borohydride fuel cell (DBFC), which lowers power output greatly. Here, we report a DBFC in which a polymer fiber membrane (PFM) was u...

Electrochemical pressure impedance spectroscopy (EPIS) has recently been developed as a potential diagnosis tool for polymer electrolyte membrane fuel cells (PEMFC). It is based on analyzing the frequency response of cell voltage with respect to an excitation gas-phase pressure. We present here combined modeling and experimental study EPIS. A pseudo-two-dimensional PEMFC model was parameterized...

We have developed a highly flexible, ultra-light and thin polymer electrolyte membrane fuel cell that can be used as a portable power source for flexible electronics. To achieve such flexibility and ultra-lightness, we fabricated a thin flow-field plate using a thermal imprinting process and combined it with a laser-machined metal current collector. The air-breathing fuel cell, with a thickness...

Environmental issues due to increases in emissions of air pollutants and greenhouse gases are driving the development of clean energy delivery technologies such as fuel cells. Low temperature Proton Exchange Membrane Fuel Cells (PEMFC) use hydrogen as a fuel and their only emission is water. W hile significant advances have been made in recent years, a major limitation of the current technology...

There has been growing interest in the modelling of proton exchange membrane fuel cells (PEMFC). While some steady-state models have been proposed, literature is scarce in PEMFC two-phase dynamic models and transient studies. Typical dynamic models for the fuel cell are empirical current-voltage dynamic models. The internal transients associated with reactant and product species and other compo...

The Proton Exchange Membrane Fuel Cell (PEMFC) control system has an important effect on operation of cell. Traditional controllers couldn’t lead to acceptable responses because of timechange, longhysteresis, uncertainty, strongcoupling and nonlinear characteristics of PEMFCs, so an intelligent or adaptive controller is needed. In this paper a neural network predictive controller have been desi...

In this paper, we introduce a modified interpretation of the water activity presented in Springer et al. [T.E. Springer, T.A. Zawodzinski, S. ottesfeld, Polymer electrolyte fuel cell model, J. Electrochem. Soc. 138 (8) (1991) 2334–2342]. The modification directly affects the membrane ater transport between the anode and the cathode (two electrodes) of the polymer electrolyte membrane (PEM) fuel...

Our previous studies demonstrated great potential of methyl methacrylate and vinylbenzyl chloride based copolymer electrolytes for alkaline fuel cell applications. In this study, a number of factors including polymer composition drift, molecular weight, and polymer crosslinking is investigated to understand their effects and to precisely control the electrolyte properties including conductivity...