The recently developed density functional theory method for pore size distribution analysis from nitrogen adsorption and desorption isotherms is extended to materials with pores ranging from 2 to 100 nm. The method is based on the nonlocal density functional theory (NLDFT) of capillary condensation hysteresis in cylindrical pores. It is shown that NLDFT correctly predicts both the adsorption an...

A two-dimensional pore-scale numerical model was developed to evaluate the dynamics of preferential flow paths in porous media caused by bioclogging. The liquid flow and solute transport through the pore network were coupled with a biofilm model including biomass attachment, growth, decay, lysis, and detachment. Blocking of all but one flow path was obtained under constant liquid inlet flow rat...

Although anaerobic membrane bioreactors (AnMBR) are widely used in high-strength wastewater treatment and resource recovery, operational performance fouling control remain critical issues. In this study, the of a high-biomass (18 ≤ MLSS (g/L) 35) submerged bioreactor (HBSAnMBR) was assessed at organic loading rates (OLR) 1.05–5 kg-COD/m3/d to treat abattoir (AWW). The correlation between kineti...

mixed clayey soils occur as mixtures of sand (or gravel) and clay in widely varying proportions. their engineering behavior has not been comprehensively studied yet. an experimental program, comprising monotonic, cyclic, and post-cyclic triaxial tests was undertaken on compacted clay-granular material mixtures, having different proportions of clay and sand or gravel. this paper presents the res...

Large degradation in thermal insulation and strain tolerance is a main headache primary cause of failure for plasma-sprayed barrier coatings (TBCs) during service. One mechanism behind such the healing interlamellar pores formed by multiple connections between edges pore, which significantly speeds up exposure. The objective this study to obtain sintering-resistant TBCs tailoring width avoid co...

Excess pore pressure under seismic loadings has always been a main concern in geotechnical engineering practices. The phenomenon in soil can cause an effective stress and hence cause the shear strength of the soil to decrease considerably and large deformations to occur in the area. Generally, increases in pore pressure occur in un-drained conditions. If it is formed, its consequences decrease ...

Dynamic Monte Carlo simulations are used to study coupled transport (co-transport) through sub-nanometer-diameter pores. In this classic Hodgkin-Keynes mechanism, an ion species uses the large flux of an abundant ion species to move against its concentration gradient. The efficiency of co-transport is examined for various pore parameters so that synthetic nanopores can be engineered to maximize...

Membrane fouling during particle filtration occurs through a variety of mechanisms, including internal pore clogging by contaminants, coverage of pore entrances and deposition on the membrane surface. In this paper, we present an efficient method for modelling the behaviour of a filter, which accounts for different retention mechanisms, particle sizes and membrane geometries. The membrane is as...

In the present study, tin-promoted Pd/MWNTs nanocatalystwas synthesized via polyol technique for application in hydrogenation of high-concentrated acetylene feedstocks. TEM images showed a restricted distribution of nanoparticles in the range of 3-5 nm. The results indicated that nanoparticles sizes were resistant to further catalyst deactivation. XRD patterns signified alloying between Pd and ...

Electrochemical and high-speed imaging techniques are used to study the abilities of ultrasonically-activated bubbles to clean out micropores. Cylindrical pores with dimensions (diameter × depth) of 500 μm × 400 μm (aspect ratio 0.8), 125 μm × 350 μm (aspect ratio 2.8) and 50 μm × 200 μm (aspect ratio 4.0) are fabricated in glass substrates. Each pore is contaminated by filling it with an elect...