A mimetic porous carbon model is generated using quench molecular dynamics simulations that reproduces experimental radial distribution functions of activated carbon. The resulting structure is composed of curved and defected graphene sheets. The curvature is induced by nonhexagonal rings. The quench conditions are systematically varied and the final porous structure is scrutinized in terms of ...

In this study, Santa Barbara Amorphous (SBA-15) mesoporous silica has been functionalized with aminopropyl groups that were converted to propargyl-bearing moieties through the reaction with propargyl bromide. The material then underwent an efficient Cu(I)-catalyzed azide alkyne click reaction with sodium azide in order to obtain the corresponding triazole products. The covalent modification of ...

conclusions while the crp value was in patients with acute brucellosis in the current study, the mpv, rdw and leukocyte counts were within the normal range. crp value remains the most valuable inflammatory marker in cases of acute brucellosis. results the follow-up within the year after treatment was examined. the values of age, gender, leukocyte count, c-reactive protein, rdw and mpv were reco...

We show that the honeycomb out-of-plane model derived by Gibson and Ashby can be applied to describe the compressive behavior of unidirectional porous materials. Ice-templating allowed us to process samples with accurate control over pore volume, size, and morphology. These samples allowed us to evaluate the effect of this microstructural variations on the compressive strength in a porosity ran...

Conventional wisdom for NMR interpretations of water-saturated porous media is that the NMR spectra are analogous to the pore size distribution of the system. This is the basis for understanding porous media as containing large vs. small pores, and is used as a justification for NMR-based permeability correlations. However, there are cases whereby issues of poor connectivity between pores can s...

A conceptual model for colloid transport is developed that accounts for colloid attachment straining, and exclusion. Colloid attachment and detachment is modeled using first-order rate expressions, whereas straining is described using an irreversible first-order straining term that is depth dependent. Exclusion is modeled by adjusting transport parameters for colloid-accessible pore space. Fitt...

c-Alumina-based materials with high porous volume, tunable pore size, were synthesized by the addition of both PEO/PPO/PEO triblock copolymers (Pluronics F127 and P123) and metal nitrates (Al, Mn, Cu) in a boehmite (AlOOH) nanoparticle hydrosol. During the subsequent thermal treatment, the surfactant was removed leaving a highly porous framework. The pore size distribution was strongly dependen...

in the current investigation a novel nano hybrid adsorbent mcm-41/n-(3-trimethoxysilyl)-propyl)diethylenetriamine (mcm-41/tmspdeta) was prepared and was characterized using dls (dynamic light scattering), fourier transform infrared (ftir), x-ray diffraction (xrd), brunauer–emmett–teller (bet) analytical techniques and transmission electron microscopy (tem). the synthesized mcm-41/tmspdeta adsor...

Where V is the adsorbed gas volume at relative pressure of P/P0; V0 maximum volume of adsorbed gas in micropores; R the universal gas constant (0.0083144 kJ/K mol); T the analysis temperature (K); and E is the adsorption energy (kJ/mol). From the linearized plot of DR equation, V0 and E are calculated. By using a conversion factor the equivalent liquid volume or micropore volume can be calculat...