Polymer coatings on nano-sized remediation agents and subsurface heterogeneity will affect their transport, likely in a pH-dependent manner. The effect of pH on the aggregation of polymer-coated nanoscale zerovalent iron (nZVI) and its deposition onto sand and clay (kaolinite) surfaces was studied. nZVI coatings included a high molecular weight (90 kg/mol) strong polyanion, poly(methacrylic aci...

The aim of the present work was to investigate poloxamer 188 (F-68) modified montmorillonite (Mt) clay as an oral drug delivery vehicle for in vitro release of anti-inflammatory drugdiclofenac sodium (DS). The clay (Mt) was treated with F-68 and the synthesized modified Mt, (F-68-Mt) was characterized by X-Ray diffraction (XRD) studies (which confirmed the intercalation of F-68 in the clay inte...

The aim of this study was the preparation of polyethylene oxide (PEO)/clay nanocomposites using organoclay produced via micellar adsorption of cethyltrimethyl ammonium bromide (CTAB) and their characterisation by X-ray diffraction (XRD), and Fourier transform infrared (FT-IR) spectra, and the investigation of certain mechanical properties of the composites. The results show that the basal dista...

We analysed the long-term variations in grain-size distribution in sediments from Gåsfjärden, a fjordlike inlet in the southwestern Baltic Sea, and explored potential drivers of the recorded changes in the sediment grain-size data. Over the last 5.4 thousand years (ky) in the study region, the relative sea level decreased 17 m, which was caused by isostatic land uplift. As a consequence, Gåsfjä...

Water-repellent soils have a potential as alternative construction materials that will improve conventional geotechnical structures. In this study, the potential of chemically treated water-repellent kaolin clay as a landfill cover material is explored by examining its characteristics including hydraulic and mechanical properties. In order to provide water repellency to the kaolin clay, the sur...

In this paper, a set of physical, geochemical and mineralogical indicators are proposed for the correlation of soil age. The parameters studied allowed the highlighting of trends in soil aging as well as the relating of these trends to specific soil forming processes. Soil aging was marked by a progressive increase in clay content and a decrease in silt/clay ratio, a slight reduction in the CEC...

Clay fractions in soils from a transect of the Mazama ash deposit (6600-yr-old) contained more than 80% amorphous material. Instrumental neutron activation analysis was used to compare the trace element composition of the soil clay with the unweathered volcanic glass. The clay fractions had only 10% as much Na as the volcanic glass. Conversely, the rare earth element concentrations were about t...

The corrosion protection of mild steel by a newly developed epoxy-based coating system containing inherently conducting nanopolyaniline-clay as a nanoadditive has been studied. Polyaniline-clay anticorrosion nanoadditive (PCNA) was obtained by the direct mixing method of nanopolyaniline (0.03 wt.%) and organo-modified clay (3 wt.%) at atmospheric pressure, and XRD technique was used to study d-...

Polymer-modified bentonite has reached significant attention in recent years, as polymers have been found to increase the resistance of clay barriers detrimental environmental conditions. Studies on polymer modification clays for barriers, most cases, address a specific with means based product. The term polymer, however, generally describes broad category macromolecules able create wide range ...