نتایج جستجو برای: reagents

تعداد نتایج: 28929  

Journal: :The Extractive Industries and Society 2022

Drawing on recent experimental and commercial developments, this review reappraises potential substitute leach reagents for cyanide in the gold mining sector. In addition to extraction, application of these processing, pre-treatment purification stages is explored. The main objective here discuss how extraction process can be more sustainable, with a view developing greener leaching reagents.

2006
F. BICKELHAUPT

Aliphatic ,w-dibromides can be converted to the corresponding c,w-di—Grignard reagents; for those members carrying less than four carbon atoms between the functions, special procedures are required. The synthesis, structure and applications of the di-Grignard reagents are discussed; particular emphasis is placed on the structures of the corresponding cyclic dialkylmagnesiums, and on the use of ...

Journal: :ACS Catalysis 2021

We describe a general catalytic methodology for the enantioselective dearomative alkylation of pyridine derivatives with Grignard reagents, allowing direct access to nearly enantiopure chiral dihydro-4-pyridones yields up 98%. The involves dearomatization in situ-formed N-acylpyridinium salts, employing alkyl organomagnesium reagents as nucleophiles and copper (I) complex catalyst. Computationa...

Journal: :Organic & biomolecular chemistry 2014
Zhihua Peng Na Li Xinyang Sun Fang Wang Lanjian Xu Cuiyu Jiang Linhua Song Zi-Feng Yan

Organomanganese reagents were prepared by the insertion of magnesium into aryl halides in the presence of MnCl2·2LiCl. These organomanganese reagents smoothly undergo 1,2-addition, acylation, and Pd-catalyzed cross-coupling with various electrophiles. Especially, the oxidative homocoupling of organomanganese reagents was completed in one pot without an additional transition-metal catalyst.

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