The acidity constants (pKa) of thirty four (34) ;-substituted carboxylic acids in aqueous solution havebeen calculated using conductor-like polarizable continuum (C-PCM) solvation model. The gasphaseenergies at the Density Functional Theory (DFT-MPW1PW91) and solvation energies atHartree Fock (HF) are combined to estimate the pKa values which are very close to the experimentalvalues where, and ...

To assess the utility of laser altimetry for studies in dynamical oceanography, we present a comparison of the Shuttle Laser Altimeter (SLA)-01 and the TOPEX/POSEIDON (T/P) radar altimeter on global and regional scales. We compare all 1.1 million SLA-01 range measurements over the oceans to the CSRMSS95 gridded mean sea surface model and find the overall root mean square (RMS) difference to be ...

the acidity constants (pka) of thirty four (34) ;-substituted carboxylic acids in aqueous solution havebeen calculated using conductor-like polarizable continuum (c-pcm) solvation model. the gasphaseenergies at the density functional theory (dft-mpw1pw91) and solvation energies athartree fock (hf) are combined to estimate the pka values which are very close to the experimentalvalues where, and ...

OBJECTIVE To compare the mean root mean square (RMS) of total higher order aberrations (HOAs), coma and spherical aberrations in individuals with myopia, hypermetropia and myopic astigmatism. METHODS This prospective analytical study was conducted at Armed Forces Institute of Ophthalmology, Rawalpindi, Pakistan from Jan 2014 to Dec 2014. Two hundred eyes of 121 patients with age ranging from ...

This paper presents an investigation into predicting the movement of a speaker’s mouth from text input using hidden Markov models (HMM). A corpus of human articulatory movements, recorded by electromagnetic articulography (EMA), is used to train HMMs. To predict articulatory movements for input text, a suitable model sequence is selected and a maximum-likelihood parameter generation (MLPG) algo...

Kinetics and selected variables (temperature, particle size and time) for extraction of Terminalia Catappa L Kernel Oil (TCKO) were investigated using solvent extraction. Kinetic models studied were: parabolic diffusion, power law, hyperbolic, Elovich and pseudo-second-order. In ascending order, the best-fitted models at the optimum temperature and oil yield were Elovich’s model, hyperbolic...

PURPOSE To evaluate the correlation between refractive error and higher-order aberrations (HOAs) in patients with myopic astigmatism. METHODS HOAs were measured using the Zywave II aberrometer over a 6 mm pupil. Correlations between HOAs and myopia, astigmatism, and age were analyzed. RESULTS One hundred and twenty-six eyes of 63 subjects with mean age of 26.4±5.9 years were studied. Mean s...

Accurate understanding of surgical tool-tip tracking error is important for decision making in image-guided surgery. In this Letter, the authors present a novel method to estimate/model surgical tool-tip tracking error in which they take pivot calibration uncertainty into consideration. First, a new type of error that is referred to as total target registration error (TTRE) is formally defined ...