Zero-current ion-flux has a great influence on the characteristics of the ion-selective electrodes. In this work the improvement of analytical performance of all-solid-state Pb(2+)-selective membrane electrodes was demonstrated by adjusting the transmembrane ion flux. The study is focused on the relationship between the conditioning solution and the linear working range of the obtained electrod...

Calibration-free coulometric determination of K+ ions was realized using an all-solid-state thin-layer laminated cell with a simple laminate structure. The fabricated consists Ag/AgCl electrode, plastic spacer for positioning the aqueous sample solution, organic ion-selective membrane, and conducting polymer/carbon electrode. An originally prepared conducting-polymer-dispersed ink cast on condu...

The ion selectivity exhibited by different types of membrane electrodes is rationalized by a theoretical treatment of the membrane potential. An equation, which is admirably suited for the interpolation of e.m.f.-values, is derived for the electrode response of membrane electrodes of the electrically neutral ligand type (antibiotics, model compounds) to mixed solutions of monovalent and divalen...

A nanocomposite membrane Cu2+ ion-selective electrode has been constructed using a new compound ethyl 1,2,3,4-tetrahydro-4-(4-methoxyphenyl)-6-methyl-2-oxopyrimidine-5-carboxylat (ETMOC) as a neutral ionophore. The electrode works properly. It responds to Cu2+ ion with a sensitivity of 29.5 ± 0.2 mV/decade over the range 1.0 × 10−9 to 5.0 × 10−1M at p...

The rapid growth of interest in the field of ion-selective electrodes (ISEs), within the larger field of electrochemical sensors based on potentiometric, amperometric, and conductometric principles, makes it highly desirable to achieve improved standardization of nomenclature in this area. The previous document, W A C Recommendations 1975 (1) has been corrected using recent experimental and the...

in the present study, a new gas diffusion electrode (gde) (based on pt/nafion membrane) is fabricated. the electrochemical results show that the new gde has the highest electrochemical activity toward the oxygen reduction reaction (orr) among the three electrodes. the sem and xrd findings show that a platinum layer can be attached to nafion membrane closely and firmly with a strong peak corresp...

in the present study, a new chemically modified carbon paste electrode (cpe) is constructed for rapid, accurate, simple, highly sensitive, and selective determination of mo (vi) using differential pulse voltammetry. the electrode was prepared using magnetic nickel zinc ferrite nanocomposite (ni0.5zn0.5fe2o4), as the modifier in cpe (ni0.5zn0.5fe2o4/cpe). mo (vi) was determined after preconcentr...

Polymeric membrane ion-selective electrodes (ISEs) have become attractive tools for trace-level environmental and biological measurements. However, applications of such ISEs are often limited to measurements with low levels of electrolyte background. This paper describes an asymmetric membrane rotating ISE configuration for trace-level potentiometric detection with a high-interfering background...