Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous resolution of conformers of a PCP pincer palladium complex ({2,6-bis[(di-t-butylphosphino)methyl]phenyl}palladium(II)halide). The crystallisation is controlled by weak hydr...

Understanding the mechanism by which advanced materials assemble is essential for the design of new materials with desired properties. Here, we report a method to form chiral, potentially porous materials through spontaneous resolution of conformers of a PCP pincer palladium complex ({2,6-bis[(di-t-butylphosphino)methyl]phenyl}palladium(II)halide). The crystallisation is controlled by weak hydr...

| The performance of second order statistics (SOS) based semi-blind channel estimation in long-code DS-CDMA systems is analyzed. The covariance matrix of SOS estimates is obtained in the large system limit, and is used to analyze the largesample performance of two SOS based semi-blind channel estimation algorithms. A notion of blind estimation e ciency is also de ned and is examined via simulat...

We explore the identifiability conditions for blind and semi-blind multiuser multichannel identification. Starting with the deterministic approach, we compare the identifiability conditions on the channel and the sources of training sequence based channel identification, blind and semi-blind channel identification. Further on, we use the stochastic approach with Gaussian priors for the source s...