Novel nanostructured materials, such as aluminum oxide (AlOOH), silicon oxide (SiO2) or zirconium oxide (ZrO2) embedded into PVA, were investigated as potential matrices to incorporate organometallic compounds (OMCs) for the development of optical oxygen-sensitive sensors which make use of the principle of luminescence quenching.

Halogenated oligosilanes and oligogermanes are interesting compounds in oligosilane chemistry from the viewpoint of silicon-based-materials. Herein, it was demonstrated that a 1,2-digermacyclobutadiene derivative could work as a bis-germylene building block towards double Si–Cl activation to give a halogenated oligometallane, a bis(chlorogermyl)dichlorosilane derivative.

A novel, solution immersed silicon (SIS)-based sensor has been developed which employs the non-reflecting condition (NRC) for a p-polarized wave. The SIS sensor's response is almost independent of change in the refractive index (RI) of a buffer solution (BS) which makes it capable of measuring low-concentration and/or low-molecular-weight compounds.

Silicon-containing particles were observed by scanning electron microscopy (SEM) in synovial fluid samples from patients with crystal-induced or inflammatory synovitis, or both. This material was an artefact produced by the technical procedures, but these particles could be easily differentiated from naturally occurring compounds by their morphology and their composition determined by analytica...

Silicon and oxygen are the two most abundant elements in the Earth's crust but despite the vast scientific literature on crystalline and amorphous silica, new chemistries, structures and applications continue to be discovered for compounds formed from these elements--thus we present here for the first time the formation of new amorphous silica structures that were uniquely synthesized by a bioi...

Sulfonated polysulfone (SPSU) with high ion exchange capacity (IEC) and ion conductivity was synthesized through deep sulfonation of polysulfone using the trimethysilyl chlorosulfonate as sulfonation agent. The silicon-containing compounds formed during the synthesis of SPSU were completely removed from the SPSU by simple evaporation. Water swelling, ion exchange capacity, conductivity and fuel...

A phosphoniafluorene and a spirobiphosphoniafluorene bearing 4-(diethylamino)styryl groups were synthesized. These compounds exhibited bathochromically shifted absorption and emission, compared with their silicon analogues, because of the strong acceptor property of the phosphonium core. They also showed enhanced two-photon absorptions at around 930 nm.

Abstract The possibilities of plasma-chemical refining metallurgical silicon have been demonstrated. It is shown that by electron-beam it possible to reduce the concentration phosphorus and boron, as well main metallic impurities evaporation both these their volatile compounds.

from the plants nutrition view point, silicon has not been recognized as an essential element but its useful effects on growth and development of many plants have been reported. in order to study the effect of application of different silicon on the yield component of wheat, an experiment was conducted in the city torbat heidarieh located in razavi khorasan province. the experiment was performe...