This study aimed to determine the effects of coating thickness and curing temperature on properties a polybutyl methacrylate-siloxane deposited structural steel S355. First, thermal sol as function were investigated using thermogravimetric analysis coupled with mass spectrometry differential scanning calorimetry. After deposition S355 dip-coating process, composition porosity evaluated Fourier ...

A siloxane-based hexacarboxylic acid (L1-H6) has been prepared and applied in MOF construction. L1-H6 itself crystallizes as an unusual interpenetrated 3D hydrogen-bonded framework. Reaction of L1-H6 with Zn(ii) gave IMP-18 - a 3D MOF incorporating Si-O-Si functionality. Cleavage of L1-H6 gives a silanol-based triacid which is shown to give a coordination polymer (IMP-19) with Zn(ii).