We define a new notion of entropy for operators on Fock spaces and positive definite multi-Toeplitz kernels on free semigroups. This is studied in connection with factorization theorems for (multi-Toeplitz, multi-analytic, etc.) operators on Fock spaces. These results lead to entropy inequalities and entropy formulas for positive definite multi-Toeplitz kernels on free semigroups (resp. multi-T...