conclusions results showed that ann is a powerful tool for predicting sorption coefficients using soil organic carbon content variations. results the multilayer perceptron (mlp) artificial neural networks (ann) model with 1-6-1 layout, predicted nearly 98% of the variance of kd as well as 94% of the koc variations with soil organic carbon content. materials and methods data of this study were d...

Improving swine effluent management practices requires understanding of the fate of nutrients derived from swine effluent in soil quality. This study was conducted to evaluate the effects of long-term swine lagoon effluent application on nutrient distribution in an alkaline Okolona silty clay, an acidic Vaiden silty clay, and a Brooksville silty clay loam. Swine effluent has been applied using ...

Inorganic phosphate may influence the adsorption of glyphosate to soil surface sites. It has been postulated that glyphosate sorption is dominated by the phosphoric acid moiety, therefore, inorganic phosphate could compete with glyphosate for surface sorption sites. We examine sorption of glyphosate in low organic carbon systems where clay minerals dominate the available adsorption sites using ...

Experiments in batch equilibrium system were carried out to evaluate the importance of physical and chemical factors determining the sorption efficiency of humic substances (HS) on aquifer material, which has been used for artificial recharge of groundwater (ARG) in drinking water production. Results showed that an increase of the amount of clay in the aquifer material and a decrease of pH in w...

abstract the availability of heavy metals in the soil is related to their partitioning between solution and solid phases and expressed by sorption isotherm. twenty surface soil samples (0-30 cm) belonging to five soil subgroups were taken from agricultural regions of western azerbaijan province. the sorption isotherms of pb were determined by equlibrating the soil with solutions containing 0, 1...

Phosphorus transfer from agricultural soils to surface waters is an important environmental issue. Commonly used computer models like EPIC have not always been appropriately updated to reflect our improved understanding of soil P transformations and transfer to runoff. Our objectives were to determine if replacing EPIC’s constant sorption and desorption rate factor (0.1) with more dynamic rate ...

The kinetics of mixed Ni-Al layered double hydroxide (LDH) precipitate formation on a soil clay fraction was monitored using X-ray absorption fine structure (XAFS) spectroscopy. The kinetic behavior was monitored at pH 6.0, 6.8, and 7.5 in order to determine the effect of reaction pH on precipitate formation. XAFS analyses were performed on a Ni-reacted whole soil at pH 7.5 to determine the eff...

introduction one concern in the disposal of municipal solid waste (msw) by landfill is the production of leachate. acidic water is capable of dissolving elements from the waste; and, as a result, the leachate can become quite contaminated. one of the heavy metals present in leachate, cadmium poses a great concern in terms of environmental contamination since it is toxic to nearly all living org...

Due to the complex nature of pesticide transport, process-based models can be difficult to use. For example, pesticide transport can be effected by macropore flow, and can be further complicated by sorption, desorption and degradation occurring at different rates in different soil compartments. We have used the Root Zone Water Quality Model (RZWQM) to investigate these phenomena with field data...

Batch experiments were conducted to study the sorption of uranium (U) onto soil in deionised water as a function of its dosage, temperature and humic acid (HA). Furthermore, soils were characterized for particle sizes in the form of sand (>63 µm), silt (>2-<63 µm) and clay (<2 µm). The textural analysis revealed that soils were admixture of mainly sand and silt along with a small abundance of c...