UV irradiation of TiO(2) loaded with bimetallic Pd-Pt alloy particles promotes highly efficient dehalogenation of organic halides with alcohol as a hydrogen source.

Dimerization of vinyl Grignard reagents and concomitant alkylation with alkyl halides have been achieved by using Cp(2)TiCl(2) as a catalyst.

The first example of a palladium-catalyzed multi-cascade reaction by simple cycloenes with aryl halides in a single operation to furnish five-contiguous-stereocenter hydronaphthoindolones is described.

This paper describes the preparation of air and moisture stable octanol derivatized crystalline silicon nanoparticles by room temperature sodium naphthalenide reduction of silicon halides.

Catalytic cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing beta-hydrogens is achieved using Fe(III) amine-bis(phenolate) halide complexes.

Purine is a ubiquitous heterocyclic scaffold of fundamental importance, and is considered to be a privileged structure in medicinal chemistry. Purine-based compounds, including N-aryl purines, exhibit a wide range of biological and pharmaceutical activities, such as antiviral, antibacterial and anticancer effects. In light of their importance, there is a surprising paucity of efficient methods ...

Halides (X=Cl, Br, I) are naturally present in water, and halide concentrations can be high water sources that impacted by salinity. also wastewater streams from various industrial operations such as pulp paper, oil gas, mining. Drinking guideline limits have been established for halides, removal is important several ways. Chloride concentration more related to salinity, its matters because of ...

Employing co-catalytic zinc reagents facilitates the iron-catalysed Suzuki cross-coupling of tetraarylborates with both benzyl and 2-heteroaryl halides.

An unprecedented copper-catalysed allylic transposition enables the regioselective synthesis of branched allylic silanes from linear allylic halides through direct C-Si bond formation.