In this study we evaluated a method for the characterization of complexes, formed in different relative ratios of mercury(II) to dicysteinyl tetrapeptide, by electrospray ionization orbitrap mass spectrometry. This strategy is based on previous successful characterization of mercury-dicysteinyl complexes involving tripeptides by utilizing mass spectrometry among other techniques. Mercury(II) ch...

Although sulfur is an essential element for marine primary production and critical for climate processes, little is known about the oceanic pool of nonvolatile dissolved organic sulfur (DOS). We present a basin-scale distribution of solid-phase extractable DOS in the East Atlantic Ocean and the Atlantic sector of the Southern Ocean. Although molar DOS versus dissolved organic nitrogen (DON) rat...

Abstract We used data from whole-lake studies to assess how changes in food quantity (phytoplankton biomass) and quality community composition, seston C:P N:P) with N fertilization affect zooplankton biomass, composition C:N:P stoichiometry, their N:P recycling ratio along a gradient lake DOC concentrations. found that despite major differences phytoplankton biomass (unimodal distributions, esp...

Possible inflexions in isothermal binding plots derived from equilibrium-dialysis measurements and in equivalent plots obtained by polarimetric measurements accord with the possibility that discrete Ca(2+)-heparin-water complexes/phases may exist, the nature and proportions of which depend on the conditions under which the interaction occurs. Analysis of the plots obtained by polarimetric study...

The binding of mithramycin A to d(ACCCGGGT)2 has been investigated by one- and two-dimensional 1H NMR spectroscopy. Titration of the drug into the octamer solution results in loss of the oligonucleotide C2 symmetry at stoichiometric ratios less than 4 drug molecules per duplex. However, at a ratio of 4:1 (drug/duplex), the C2 symmetry of the oligonucleotide is restored. From these data it is ev...

Packaging multiple small interfering RNA (siRNA) molecules into nanostructures at precisely defined ratios is a powerful delivery strategy for effective RNA interference (RNAi) therapy. We present a novel RNA nanotechnology based approach to produce multiple components of polymerized siRNA molecules that are simultaneously self-assembled and densely packaged into composite sponge-like porous mi...

While many harmful algal blooms have been associated with increasing eutrophication, not all species respond similarly and the increasing challenge, especially for resource managers, is to determine which blooms are related to eutrophication and to understand why particular species proliferate under specific nutrient conditions. The overall goal of this brief review is to describe why nutrient ...

Reclaimed coastal areas were mostly used for agricultural purposes in the past, while land-use conversion was initiated recent decades eastern China. Elucidation of effects on soil properties and stoichiometry is essential addressing climate change ecological conservation. In this study, five types a reclaimed area chosen to compare differences stoichiometry, which comprised paddy, upland, upla...

Upwelling and the biological pump in Southern Ocean control amount stoichiometry of nutrients available for lateral export to lower latitudes, thereby collectively acting as a gatekeeper global thermocline nutrient distribution ocean productivity. Yet, exact role played by phytoplankton its community composition this gatekeeping has not been well established. Here, we investigate using high-res...