High-resolution liquid- and solid-state 119Sn NMR spectroscopy was used to study the bonding environment in the series of monomeric, two-coordinate Sn(II) compounds of formula Sn(X)C6H3-2,6-Trip2 (X = Cl, Cr(eta 5-C5H5)(CO)3, t-Bu, Sn(Me)2C6H3-2,6-Trip2; Trip = C6H2-2,4,6-i-Pr3). The trends in the principal components of the chemical shift tensor extracted from the solid-state NMR data were con...

Title of Document: TIN WHISKER RISK ASSESSMENT STUDIES Tong Fang, Doctor of Philosophy, 2005 Directed By: Professor Michael G. Pecht Department of Mechanical Engineering As a result of the global transition to lead (Pb)-free electronics, pure tin and high tin lead-free alloys have been widely adopted by the electronics part manufacturers as the materials of terminal finishes. However, electrica...

Objectives: Searching for testicular intraepithelial neoplasia (TIN; carcinoma in situ) in the contralateral testis of patients with germ cell tumour (GCT) may early disclose contralateral GCT. A single biopsy of the testis is thought to accurately detect TIN. Reports on false-negative biopsies have challenged this view. We investigated whether systematic two-site biopsies are more sensitive th...

ABSTRACT. Zinc(II), cadmium(II), tin(II), lead(II) and antimony(III) complexes of creatinine with the composition [M(creat)2Xn].xH2O, (X = Cl or NO3; n 2-6) were prepared. The characterized by analytical spectral methods. analysis FT-IR Raman spectra helps to understand coordination properties ligand determine probable structure complexes. shift in resonances cyclic NH proton 1H NMR when compar...

In this report, both p- and n-type tin oxide thin-film transistors (TFTs) were simultaneously achieved using single-step deposition of the tin oxide channel layer. The tuning of charge carrier polarity in the tin oxide channel is achieved by selectively depositing a copper oxide capping layer on top of tin oxide, which serves as an oxygen source, providing additional oxygen to form an n-type ti...

In this work, TiN/TiCN & PN/TiCN multilayer films were deposited by plasma- assisted chemical vapour deposition (PACVD). Plasma nitriding (PN) and TiN intermediate layer prior to coating leads to appropriate hardness gradient and it can greatly improve the mechanical properties of the coating. The composition, crystalline structure and phase of the films were investigated by X-ray d...

Iproplatin is a quadrivalent second-generation platinum complex undergoing clinical evaluation. In plasma and urine of patients receiving this drug, iproplatinand platinum-containing metabolites of iproplatin were separated by reverse-phase gradient high performance liquid chromatography. One of the metabolites was identified by cochromatography and electron impact mass spectrometry as cu-dichl...