We report on the design of practical surface enhanced Raman scattering (SERS) substrate based upon 3D alumina membranes with cylindrical nanopores chemically modified with polyelectrolyte coating and loaded with gold nanoparticle clusters. These substrates allow for a molecular-level, label-free detection of common plastic explosive materials (TNT, DNT) down to 5-10 zeptograms or 15-30 molecule...

The assessment of indoor air volatile organic compounds (VOCs) concentration levels in dental settings has a big health relevance for the potentially massive occupational exposure to a lot of diverse contaminants. The comparison of the VOCs profile relative to indoor conditions and to the corresponding outdoor concentrations, as well as the discovery of possible correlations between specific de...

phy 665: 243. Junk GA, Richard JJ, Grieser MD et al. (1974) Use of Macroreticular resins in the analysis of water for trace organic contaminants. Journal of Chromatography 99: 745. Puig D and BarceloH D (1995) Off-line and on-line solidphase extraction followed by liquid chromatography for the determination of priority phenols in natural waters. Chromatographia 40: 435. Puig D and BarceloH D (1...

C288 this compound is crystallized from solutions in acethophenone as a host-guest complex with a ratio 2:3. In the crystal structure DEDA molecules form infinite chains in a direction [01-1] through a pair of centrosymmetric hydrogen bonds. The acethophenone molecules are situated inside different channels formed at stacking of these chains and running along [100] and [0-11] directions. At dec...

Permeation tubes are convenient analyte sources for generating standard gas mixtures (containing, in particular, volatile organic compounds) used in the calibration of analytical instruments. For small permeation rates, corresponding to trace levels of analytes, the calibration of permeation tubes is time-consuming. The use of thermogravimetry as a means to measure rapidly the weight loss at co...

The dynamic method of generating reference Volatile Organic Compounds (VOC) mixtures at trace level requires the uninterrupted blending of the component flows. The accurate control of the dilution air flows can be realized by Mass Flow Controllers (MFC). Accuracy and stability of MFC are here measured and discussed in order to verify their use in dynamic gas dilutors. Long term stability confir...

The present paper reviews some paradigmatic applications of modeling and simulation in the context of exhaled breath analysis, which has emerged as a promising tool for collecting non-invasive and continuous information on the metabolic and physiological state of an individual. In particular, it is illustrated how real-time breath profiles of volatile organic compounds (as obtained, e.g., by PT...

The atmosphere is an oxidizing medium. Many environmentally important trace gases emitted from the Earth’s surface are removed from the atmosphere by oxidation. The list includes methane and other organic compounds, carbon monoxide, nitrogen oxides, and sulfur gases (Table 1). Understanding the processes and rates by which species are oxidized in the atmosphere, i.e., the oxidizing power of the...

Introduction Conclusions References

The phytodegradation of organic compounds can take place inside the plant or within the rhizosphere of the plant. Many different compounds and classes of compounds can be removed from the environment by this method, including solvents in groundwater, petroleum and aromatic compounds in soils, and volatile compounds in the air. Although still a relatively new area of research, there are many lab...