We report the simultaneous measurement of conductance and thermopower of highly conducting single-molecule junctions using a scanning tunneling microscope-based break-junction setup. We start with molecular backbones (alkanes and oligophenyls) terminated with trimethyltin end groups that cleave off in situ to create junctions where terminal carbons are covalently bonded to the Au electrodes. We...

The reaction of 1,1'-ferrocenedicarboxylic acid (LH(2)) with bis(triphenyltin) oxide afforded a molecular heterobimetallic compound [(Ph(3)Sn)(2)L]. In the latter the two carboxylate units of [L](2-) are involved in an anisobidentate chelating coordination mode to two triphenyl tin units. The reaction of LH(2) with trimethyltin hydroxide or bis(tri-n-butyltin) oxide afforded 2D-coordination pol...

results in all the groups, complete hemostasis occurred. hemostasis times of different concentrations of zinc chloride were significantly less than that of the control group (p < 0.001). objectives this study aimed to compare haemostatic effect of zinc chloride and simple suturing to control external bleeding. materials and methods in this animal model study, 60 male wistar rats were used. an i...

the solvent free route for the synthesis of diaryl sulfoxides from arenes and thionyl chloride in the presence of lewis acids such as aluminum chloride and ferric chloride on silica gel are described.

abstract heavy metals are the important pollution which there is in the aquatic ecosystems. today, with advances in technology have increased the pollution therefore it is important to assessment the risks. the aim of this study was acute toxicity effects of mercury chloride, lead chloride and zinc chloride in silver carp fish. in this study there were 5 treatments for lead chloride and mercury...

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