The triphenyl-methyl group in the title compound, C(28)H(23)IO(2)S, has the methine carbon slightly flattened out [ΣC(phen-yl)-C-C(phen-yl) = 332.8 (6) °]. The -C-O-C-C-S- chain connecting the triphenyl-methyl group and the aromatic ring adopts an extended zigzag conformation, these five atoms being approximately co-planar (r.m.s. deviation 0.260 Å).

In this paper, the chemical Functionalization of Carboxylate multi-walled carbon nanotubes by methyl (triphenyl phosphoranylidene) acetate have been investigated. Phosphorus Ylides are important compound in organic chemistry. At first, methyl (triphenyl phosphoranylidene) acetate, synthesized from salt metod in two steps: the formation of the phosphonium salt and the deprotonation of the latter...

A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.

In this paper, the chemical Functionalization of Carboxylate multi-walled carbon nanotubes by methyl (triphenyl phosphoranylidene) acetate have been investigated. Phosphorus Ylides are important compound in organic chemistry. At first, methyl (triphenyl phosphoranylidene) acetate, synthesized from salt metod in two steps: the formation of the phosphonium salt and the deprotonation of the latter...

Manganese-oxo complexes have long been investigated because of their proposed roles in biological and chemical catalysis. However, there are few examples of monomeric complexes with terminal oxo ligands, especially those with oxomanganese(IV) units. A oxomanganese(IV) complex has been prepared from [MnIIIH3buea(O)]2- ([H3buea]3-, tris[(N'-tert-butylureaylato)-N-ethylene]aminato), a monomeric Mn...

The aim of this work was to synthesize and investigate properties of a novel dimethacrylic monomer based on bioderived alicyclic diol--isosorbide. Its potential as a possible substitute of 2,2-bis[4-(2-hydroxy-3-methacryloyloxypropoxy)phenyl]propane (BISGMA), widely used in dental restorative materials and suspected for toxicity was assessed. The novel monomer was obtained in a three-step synth...

The title compound, C(26)H(20)N(2), first reported in 1891, was obtained as a by-product in the preparation of benzildianil from benzil and excess aniline. The dihedral angles between the fused benzene ring and the pendant phenyl rings are 17.93 (11), 53.18 (10) and 89.08 (12)°.

The aim of this study is to identify the biochemical mechanism of phosphine toxicity and resistance, using Caenorhabditis elegans as a model organism. To date, the precise mode of phosphine action is unclear. In this report, we demonstrate the following dose-dependent actions of phosphine, in vitro: (1) reduction of ferric iron (Fe3+) to ferrous iron (Fe2+), (2) release of iron from horse ferri...

Highly phosphine-resistant populations of Rhyzopertha dominica (F.) (Coleoptera: Bostrichidae) and Tribolium castaneum (Herbst) (Coleoptera: Tenebrionidae) have recently been found in Oklahoma grain storage facilities. These Þndings necessitate development of a phosphine resistance management strategy to ensure continued effective use of phosphine. Therefore, we investigated the efÞcacies of tw...