A spectrophotofluorometer capable of continuous activation of solutions and measurement of resultant fluorescence throughout the quartz-ultraviolet and visible regions of the spectrum has been previously described (1). The ability of such an instrument to deliver high intensity monochromatic light at the absorption maxima of tryptophan and tyrosine, and to measure the resulting ultraviolet fluo...

Two new products were isolated from uracil irradiated with ultraviolet light in frozen aqueous solution. As judged by mass, nuclear magnetic resonance, and ultraviolet and infrared spectra, one is a photopolymer, U(3) and the structure of the other is probably 6-4'-[ pyrimidin-2'-one]-uracil. Formations of these products between pyrimidine bases are apparently common photoreactions, and may be ...

We present and discuss near-ultraviolet and optical ground-based spectra of the 20 brightest Seyfert 2 nuclei, and HST ultraviolet images and ultraviolet spectroscopy for a few of them. The goal is to study the starburst-AGN connection and the origin of the featureless continuum. The results indicate that half of the nuclei in the sample harbor a young and/or intermediate age population. These ...

A considerable interest is growing worldwide about the photobiological effects of the ultraviolet radiation; in fact, it has been demonstrated that ultraviolet radiation can affect both human health as well as the equilibrium of entire ecosystems. The relative effectiveness of ultraviolet radiation at a particular wavelength in producing a specific biological response is defined by an action sp...

Excitation energies, oscillator strengths, and vacuum-ultraviolet/deep-ultraviolet absorption spectra were calculated for nerve agents, such as sarin, soman, VX, tabun, mustard gas, and analogs. We used time-dependent density functional theory (TD-DFT) methods that included B3LYP combined with basis sets of cc-pVDZ and cc-pVTZ, and ωB97XD with cc-pVTZ. The vertical ionization energies were also...

The computational modelling and total antioxidants activities of three N-(methoxysalicylidene) anilines namely N- (methoxysalicylidene)aniline [I], N-(methoxysalicylidene)-4-chloroaniline [II] N-(methoxysalicylidene)-5-chloro-2-methylaniline [III] were reported. compounds synthesized characterized by elemental analysis, infrared, ultraviolet, proton carbon-13 nuclear magnetic resonance. Quantum...

We present ultraviolet spectra of Mira’s companion star from the Space Telescope Imaging Spectrograph (STIS) instrument on board the Hubble Space Telescope (HST). The companion is generally assumed to be a white dwarf surrounded by an accretion disk fed by Mira’s wind, which dominates the UV emission from the system. The STIS UV spectrum is dominated by numerous, narrow H2 lines fluoresced by H...

Calculated circular dichroism spectra are presented for double-stranded polynucleotides of regular sequences in A-RNA, A-DNA, B-DNA, and Z-DNA conformations. Quantum mechanical matrix method calculations were carried out in the near and vacuum ultraviolet regions. In the near UV, the calculated spectra agreed qualitatively with the measured spectra. However in the far and vacuum UV, the calcula...

We present and analyze Hubble Space Telescope observations of the eclipsing nova-like cataclysmic variable UX UMa obtained with the Faint Object Spectrograph. Two eclipses each were observed with the G160L grating (covering the ultraviolet waveband) in August of 1994 and with the PRISM (covering the near-ultraviolet to near-infrared) in November of the same year. The system was ∼50% brighter in...