نتایج جستجو برای: vanadyl complexes

تعداد نتایج: 137493  

Journal: :Chemical Science 2021

We show that a sizeable electronuclear entanglement of the S = 1/2 and I 7/2 spins vanadyl porphyrin provides conditions to act as universal 4-qubit processor, thus implement quantum error correction at molecular level.

2013
Huong Giang T. Nguyen Mitchell H. Weston Amy A. Sarjeant Daniel M. Gardner Zhi An Raanan Carmieli Michael R. Wasielewski Omar K. Farha Joseph T. Hupp SonBinh T. Nguyen

Through a combination of protecting groups, postsynthesis deprotection, and postsynthesis metallation, a homogeneously inaccess ible , s ingle-s i te vanadyl(monocatecholate) moiety can be incorporated into the dipyridyl struts of a Zn-based, pillared paddlewheel MOF. The resulting MOF, which has large pores, exhibits catalytic activity in the benzylic oxidation of tetralin in the presence of t...

2011
Safa Ezzine Yahmed Mohamed Faouzi Zid Ahmed Driss

The vanadyl arsenate, VOAsO(4), has been isolated by a solid-state reaction. The structure consists of distorted VO(6) octa-hedra and AsO(4) tetra-hedra sharing corners to build up VAsO(7) layers parallel to ac linked by edge-sharing of VO(6) octa-hedra, forming a three-dimensional framework.

Journal: :Chemical communications 2009
Shaoqiang Dong Hongkun Tian De Song Zhenhua Yang Donghang Yan Yanhou Geng Fosong Wang

Tetraoctyl-substituted vanadyl phthalocyanine (OVPc4C8) as a new NIR-absorbing discotic liquid crystalline material can form highly ordered thin films with edge-on alignment of the molecules and molecular packing mode identical to that in the phase II of OVPc for solution processed OTFTs with mobility up to 0.017 cm(2) V(-1) s(-1).

G.A. Dehghani G.H. Omrani S. Mansoorzadeh S.Z. Tabeei

Background: It is known that vanadyl compounds are capable of alleviating hyperglycemia in streptozotocin induced diabetic rats. Objective: To examine the effect of vanadyl sulphate (VS) on spermatogenesis of male rats. Methods: Male rats (n=10) were administered 32 mg/kg/day of VS orally and 50 mEq/l NaCl (as drinking water) for one month.  Meanwhile, 11 male rats, the control group, received ...

Journal: :The Journal of clinical endocrinology and metabolism 2001
K Cusi S Cukier R A DeFronzo M Torres F M Puchulu J C Redondo

Vanadyl sulfate (VOSO(4)) is an oxidative form of vanadium that in vitro and in animal models of diabetes has been shown to reduce hyperglycemia and insulin resistance. Small clinical studies of 2- to 4-week duration in type 2 diabetes (T2DM) have led to inconsistent results. To define its efficacy and mechanism of action, 11 type 2 diabetic patients were treated with VOSO(4) at a higher dose (...

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