Milk fat was fractionated into liquid (m.p. congruent to 12 degrees C), intermediate (m.p. congruent to 21 degrees C) and solid (m.p. congruent to 39 degrees C) fractions by three different processes--melt crystallization, short-path distillation and supercritical CO2 extraction--and the cholesterol content of these fractions determined. Cholesterol was enriched in the liquid fractions from all...

Combustion Thermodynamics ...................................................................................................................... 1 Combustion ............................................................................................................................................... 1 Thermodynamics fundamentals ....................................................................

This paper focusses on the characteristics of persistent, thin single-layer mixed-phase clouds. We seek to answer two important questions: (i) how does ice continually nucleate and precipitate from these clouds, without the available ice nuclei becoming depleted? (ii) how do the supercooled liquid droplets persist in spite of the net flux of water vapour to the growing ice crystals? These quest...

The Gibbs-Bogoliubov formalism in conjunction with the pseudopotential theory is applied to the calculation of the vapour pressure of eight liquid metals from Groups I to IV of the periodic table and of alloys (Na-K). The calculated vapour pressure o f the elements and their temperature dependencies, the partial pressures, activities and boiling points of the alloys are all found to be in reaso...

Phase transformations such as freezing typically start with heterogeneous nucleation. Heterogeneous nucleation near a wetting transition, of a crystalline phase is studied. The wetting transition occurs at or near a vapour-liquid transition which occurs in a metastable fluid. The fluid is metastable with respect to crystallisation, and it is the crystallisation of this fluid phase that we are i...

In recent years, ionic liquids have become increasingly attractive as 'green solvents' used in the extraction of bioactive compounds from natural plant. However, the separation of ionic liquid from the target compounds was difficult, due to their low vapour pressure and high stabilities. In our study, ionic liquid-based ultrasonic and microwave-assisted extraction was used to obtain the crude t...

The use of the Maxwell construction, in conjunction with the van der Waals equation of state, to represent the liquefaction of gases is familiar to all students of thermodynamics. The present paper is concerned with the application of the Maxwell construction to Fermi fluids, and in particular with the question as to whether or not they can undergo a liquid-gas phase transition at T= 0. We shal...

in this study, liquid-liquid extraction process in a kuhni extraction column was modeled and simulated. a non-equilibrium dynamic model was developed for modeling liquid-liquid extraction processes based on a rate-based model. the model equations are inclusive of partial and ordinary differential equations which were discretized in column height direction. the population balance model was used ...

• Analysis of formation and development cavitation a multicomponent Diesel fuel surrogate discharging from high-pressure injector. Two approaches have been followed: (i) barotropic evolution (ii) the inclusion wall friction-induced pressurisation thermal effects. The preferential components within injector's hole is predicted by Vapour-Liquid Equilibrium calculations. Results indicate significa...