ZIF-94 is a zeolitic imidazolate framework with the same SOD type topology than ZIF-8 but an aldehyde group functionalized organic ligand. This turns less thermally stable interesting properties of water and carbon dioxide adsorption, making former material highly suitable for capture technologies. In this work, alternative procedure synthesis was developed based on use NaOH as deprotonator. Be...

Mechanochemical dry conversion that only uses zinc oxide and an imidazole ligand proved to be effective and reliable for fabrication of a zeolitic imidazolate framework with a polycrystalline grain boundary and a core-shell structure. The zinc oxide crystals are converted into a zeolitic imidazolate framework to a depth of approx. 10 nm below the surface.

LiFePO4 is one of the industrial, scalable cathode materials in lithium-ion battery production, due to its cost-effectiveness and environmental friendliness. However, electrochemical performance high current rate operation still limited, poor ionic- electron-conductive properties. In this study, a zeolitic imidazolate framework (ZIF-8) multiwalled carbon nanotubes (MWCNT) modified LiFePO4/C (LF...

This work aims to shed light on the performance of zeolitic imidazolate frameworks for hydrogen purification from coke oven gases (COG). Using molecular simulation, we model COG as a mixture six and study effect ZIF topology separation performance. To do this, compare similar structures, e.g., ZIF-8 ZIF-11, focus obtaining information that explains why they behave differently while being so sim...

To meet society’s need for more and specialized materials, this work focuses on the preparation of porous metal–organic framework (MOF)–zeolite hybrid materials based two 2D zeolites, namely, IPC-1P (Institute Physical Chemistry - 1 Precursor) ZIF-8 (Zeolitic Imidazolate Framework-8). Using previously well-established assembly–disassembly–organization–reassembly method, zeolite was (i) synthesi...

Zeolitic imidazolate frameworks (ZIFs), a subclass of metal–organic (MOFs), have been widely investigated as additive in mixed matrix membranes (MMMs), but systematic studies to identify critical intrinsic ZIF-type parameters that determine the MMM performance are lacking. Therefore, three isoreticular gmelinite (GME) ZIFs, i.e., ZIF-68, 69 and 78 distinct by their partial different linkers, we...