PURPOSE Translucency of all-ceramic restorations is an important factor which affects the final appearance and esthetic outcome of the restoration. The aim of this study was to evaluate the effect of the shade of coloring liquid on the translucency of zirconia framework. MATERIALS AND METHODS Thirty zirconium oxide core plate (15 × 12 × 0.5 mm) were divided into 6 groups of 5 plates each. Eac...

With the motivation of exploring new high-strength ceramics, ab initio evolutionary simulations are performed to search for all the stable compounds in the Zr-O system. We have found that not only the traditional compound ZrO2, but also the ordered suboxides R3̅-Zr6O, R3̅c-Zr3O, P3̅1m-Zr2O and P6̅2m-ZrO are stable at zero pressure. The crystal structure of semimetallic P6̅2m-ZrO consists of Zr-graph...

Here we describe a simple route to creating conformal sulphated zirconia monolayers throughout an SBA-15 architecture that confers efficient acid-catalysed one-pot conversion of glucose to ethyl levulinate.

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Nanocrystallite ceria-doped scandia-stabilized zirconia (1Ce10ScSZ) powders are prepared using a combination of co-precipitation and hydrothermal treatments. Power density of 1.0 W cm(-2) is obtained at 1.6 A cm(-2) and 800 °C due to the drastic reduction of ohmic and polarization resistance in the SOFC cell.

Recent developments in solid-oxide fuel cells (SOFC) that electrochemically oxidize hydrocarbon fuels to produce electrical power without first reforming them to H2 are described. First, the operating principles of SOFCs are reviewed, along with a description of state-of-the-art SOFC designs. This is followed by a discussion of the concepts and procedures used in the synthesis of direct-oxidati...

Elecln~chemic~d pn~:es~c~ occun'ing ,*kt fire inlerf~lce platinnmly|lria==~,~l~lbilized zirconia were investigaled by cyclic vol|aml)]¢lry and polentiostalic currenlo~poleatial curves, laken n|lder ~leatly~slate condilions, in different mixtures of oxygen and nitrogen at ~e|nperalures between 3tX) and fi00°C. Point or paste electrt~des were used~ The exchange ctnxenl of |be rate-determining sle...

Zirconia as a restoration dental material are gaining attention because of their high mechanical properties and good biocompatibility. Therefore, investigation of the flexural strength of zirconia is of great interest. For this purpose, Weibull statistics for description of the material reliability are frequently used. The aim of this work was to present a blinded data set to two independent st...

J. WANG

Zirconia (ZrO2) is a well known oxide refractory material, possessing high strength and high melting point. Black zirconia is a variant of conventional zirconia obtained by the addition of a pigments percentage which changes its color from white to black. The present work shows, for the first time to the best of our knowledge, optical spectra of black ZrO2 in the range 0.3-16.3 μm, comparing th...