1. Introduction Mesoporous UL-ZSM-5 materials have zeolitic structure in the form of nano-particles inter-grown in the walls of the amorphous wormhole-like aluminosilicate mesoporous precursor, and were shown to exhibit an intermediate acidity between the parent mesoporous precursor and ZSM-5 zeolite [1,2]. These materials combine the advantages of both, i.e., microporous crystalline zeolites (...

‘H magic angle spinning nuclear magnetic resonance (MAS NMR) measurements on ZSM-5 synthesized with tetrapropylammonium ions as structure-directing template, calcined and hydrogen exchanged, indicate high concentrations of silanol groups (up to 4.6~ 10zo SiOH g-‘)_ ‘H NMR, “Na and % MAS NMR studies of zeolites ZSM-5 with different Si/Al ratios support a model which attributes the majority of th...

Zeolite micropattern created from structurally similar hydrophobic Sil-1 and hydrophilic ZSM-5 zeolites, and tested for the immobilization of fluorescein isothiocyanate conjugate bovine serum albumin (BSA-FITC), biotin conjugate bovine serum albumin (Biotin-BSA), Hochest 33342 and rhodamine conjugate αbungatoxin, were preferentially deposited onto hydrophobic ZSM-5 patterns regardless of the pa...

zeolite zsm-5 presents a great source of interest in catalysis because of its shape selective properties. the absence of a relationship between the template size and shape of the structure generated during the synthesis of zeolites is illustrated by the case of zsm-5. in this study, we have investigated the role of ethanol, methyltriphenylphosphonium bromide (mtpbr) and cetyltrimethylammonium b...

ZSM-5 is an important class of acid catalyst for producing bio-oil rich in petrochemicals; however, continuous efforts are required to improve the conversion efficiency biomass-derived oxygenates with large molecular sizes. The mesoporous (N-ZSM-5) was prepared a post-treatment method nanocellulose as green template this study induce additional surface and porous features. promoted properties N...

abstract aims: the application of photocatalytic processes to remove heavy metals in aqueous solutions and industrial wastewater are regarded as extremely effective, clean and without producing waste methods. the goal of the present study was to investigate the photocatalytic activity of zno based on h-zsm-5 zeolite support. materials & methods: zno/h-zsm-5 composite synthesized by impregnation...

γ-Valerolactone (GVL) is one of the useful biomass compounds produced via different reaction pathways from hemicellulose. In this study, Co- and Pt-doped/ZSM-5 catalysts with Co loadings (0–10 wt.%) Pt (0.5–2 were prepared by impregnation method employed in a one-pot conversion furfural to GVL. The yield GVL increased increasing temperature 100 140 °C. At 120 °C, higher amounts secondary produc...

An equilibrated mixture of pentene isomers was produced by dehydroisomerization of n-pentane on catalysts consisting of Pt clusters within [Fe]ZSM-5 channels. These catalysts showed high isomerization rates, excellent stability even without added H2, and isopentene selectivities above 60%. Metal sites on Pt clusters dehydrogenate n-alkanes and n-alkenes formed undergo skeletal rearrangements wi...