Highly piezoelectric and pyroelectric phases of boron-nitrogen-based polymers have been designed from first principles. They offer excellent electrical and structural properties, with up to 100% improvement in the piezoelectic response and an enhanced thermal stability with respect to polyvinylidene fluoride (PVDF). Since methods for their synthesis are readily available, these polymers are ext...

We report a new United Atom Force Field (denoted MSUA) for molecular dynamics simulation of the uoro polymers: Poly(tetra uoroethylene) (PTFE), Poly(vinylidene uoride) (PVDF), and Ethylene-tetra uoroethylene (ETFE). The MSUA was obtained from combining quantum chemistry and experimental results. Using the MSUA and periodic boundary conditions, we carried out molecular dynamics simulations using...

This study analyses the possibility of reprocessing used poly(vinylidene fluoride), PVDF, maintaining the main properties critical for its use in piezoelectric sensor/actuator applications. The influence of multiple reprocessing cycles of PVDF on crystallinity and ß-phase content fundamental for its electroactive behaviour, was studied. Nine reprocessing cycles were completed and it was found t...

High safety and rate capability of lithium-ion batteries (LIBs) remain challenging. In this study, sandwich-structured poly(vinylidene fluoride)/poly(vinylidene fluoride-co-hexafluoropropylene)/poly(vinylidene fluoride) (PVDF/PVDF-HFP/PVDF) membranes with thermal shut-down function were successfully prepared through electrospinning. The effects different weight ratios PVDF PVDF-HFP in a composi...

The redshift-space correlation function ξs for projected galaxy separations <∼ 1h Mpc can be expressed as the convolution of the real-space correlation function with the galaxy pairwise velocity distribution function (PVDF). An exponential PVDF yields the best fit to the ξs measured from galaxy samples of different redshift surveys. We show that this exponential PVDF is not merely a fitting fun...

A flexible 4 × 4 sensor array with 16 micro-scale capacitive units has been demonstrated based on flexible piezoelectric poly(vinylidene fluoride) (PVDF) film. The piezoelectricity and surface morphology of the PVDF were examined by optical imaging and piezoresponse force microscopy (PFM). The PFM shows phase contrast, indicating clear interface between the PVDF and electrode. The electro-mecha...

In this work, a supported ionic liquid membrane (SILM) was prepared by impregnating a PVDF membrane with 1-butyl-3-methylimidazolium dicyanamide ([BMIM][DCA]) ionic liquid. This membrane was tested for its permeability to pure gases (CO2, N2 and O2) and ideal selectivities were calculated. The SILM performance was also compared to that of Ion-Jelly® membranes, a new type of gelled membranes dev...

This paper presents the development of a biomimetic sensor, with the ability to imitate exteroceptor and proprioceptor functions of invertebrates, such as earthworms. A polyvinylidene fluoride (PVDF) film is selected as the sensing element because it is flexible, highly sensitive and easy to be integrated in different shapes. Perforated PVDF strips are embedded in a segmented silicone shell of ...

We compare the photoemission and electron energy loss spectra of crystalline poly(vinylidene-fl uoride with trifl uoroethylene: 70%: 30%), P(VDF–TrFE), fi lms, fabricated by the Langmuir–Blodgett technique and annealed in vacuum, with in situ thermally evaporated fi lms of poly(vinylidene-fl uoride) (PVDF) in vacuum. Th e electronic structure and vibrational modes of the short chain PVDF fi lms...