Pyruvate is an endogenous antioxidant substance. The aim of this study was to investigate the protective effects of ethyl pyruvate (EP) on retinal vascular injury in diabetic retinopathy. To investigate the protective effect of EP on vascular cell apoptosis and blood-retinal barrier (BRB) breakage, we have used intravitreally methylglyoxal-(MGO-) injected rat eyes. Apoptosis of the retinal vasc...

The surface topography and local surface work function of ultrathin MgO(001) films on Ag(001) have been studied by noncontact atomic force microscopy (nc-AFM) and Kelvin probe force microscopy (KPFM). First principles calculations have been used to explain the contrast formation of nc-AFM images. In agreement with literature, thin MgO films grow in islands with a quasi rectangular shape. Contra...

present success was attained by making various technical developments, such as a liquid-solid hybrid system and indium bond between sample and buffer-rod. Analytical procedures were also developed both in required corrections for apparent travel times, and in formulation of pressure effect on elasticity. A distinct shear softening was found in MgAl2O4, and was predicted to occur in MgO beyond 3...

Stilbenediamine is used as derivatizing reagent for methylglyoxal (MGo) and dimethylglyoxal for the gas chromatographic (GC) determination of MGo from the serum of diabetic patients and healthy volunteers. The derivatization is obtained at pH 3. GC elution and separation are carried out on an HP5 column (30 m x 0.32 mm i.d.) at column temperature 150 degrees C with a programmed heating rate of ...

The coadsorption of methanol (CH3OH) and water (D2O) on the MgO~100!/Mo~100! surface at 100 K has been studied by metastable impact electron spectroscopy ~MIES!, ultraviolet photoelectron spectroscopy @UPS ~HeI!#, and by thermal programmed desorption ~TPD!. Methanol wets the MgO surface and adsorbs nondissociatively within the first monolayer with the hydroxyl group oriented toward the substrat...

It was found that in double MgO based perpendicular magnetic tunneling junction spin-valves ex-situ annealed at 400 °C, the tunneling magnetoresistance ratio was extremely sensitive to the material and thickness of the nanoscale spacer: it peaked at a specific thickness (0.40~0.53 nm), and the TMR ratio for W spacers (~134%) was higher than that for Ta spacers (~98%). This dependency on the spa...

Fe/MgO/Fe magnetic tunnel junctions (MTJs) have been reported to have very high tunnel magnetoresistance (TMR) ratios. In this work, we present the results of First Principle simulations of Fe/ MgO/Fe MTJs with LSDA as the exchange correlation. The I-V characteristics in the antiparallel magnetization state exhibit strong features. The bias dependence of the TMR ratio shows nearly 100% TMR rati...

We describe a highly nanodispersed Pd-MgO/SiO(2) composite catalyst synthesized by an in situ, one-pot, reverse microemulsion method as a multifunctional catalyst for low-temperature CH(4) reforming. Experimental results suggested evidence for a synergistic interplay of each component and DFT calculations confirmed a multifunctional reaction mechanism of CH(4) reforming and the importance of th...

We have studied the magnetoresistance of single-crystalline 001 Fe films prepared by sputtering techniques and covered by epitaxial MgO or Pt protective layers. The influence of the thickness of the magnetic layer as well as of the nature of the capping layer on the Fe anisotropic magnetoresistance was investigated by four-terminal probe, measurements performed with the current J in the 110 mag...

We report on the structural evolution versus thickness of MgO thin films grown epitaxially on Mo(001) and on the correlation between structure and surface morphology. The misfit strain induced by the mismatch with the substrate is relieved between 1 and 7 ML MgO due to the formation of an ordered network of interfacial misfit dislocations aligned along the MgO <110> directions, particularly evi...