Molecular/theoretical modeling studies have revealed that thyroid hormones and toxic chlorinated aromatic hydrocarbons of environmental significance (for which dioxin or TCDD is the prototype) have similar structural properties that could be important in molecular recognition in biochemical systems. These molecular properties include a somewhat rigid, sterically accessible and polarizable aroma...

A series of field studies was conducted between 1979 and 1985 in Puget Sound, Washington State, to investigate etiological relationships between prevalences of hepatic neoplasms in bottom-dwelling marine fish species, with emphasis on English sole (Parophrys vetulus), and concentrations of toxic chemicals in sediments and affected fish. Statistically significant (p less than or equal to 0.05) c...

The paper is a contribution for the knowledge upon concentrations and fate of different kinds of organic micropollutants in Tropical River system from a very industrialized region in Brazil. The presented data was obtained during three years of an International Research Project between Brazilian and Dutch institutions. The sediments were sampled at the Paraiba do Sul-Guandu river watershed, the...

The waste tyres represent a source of energy and valuable hydrocarbon products. Waste tyres were pyrolysed catalytically in a batch reactor under atmospheric pressure. The effects of basic catalysts (MgO and CaCO3) were studied on the pyrolysis products. The distribution ratio of gas, liquid and char with MgO and CaCO3 were 24.4:39.8:35.8 wt % and 32.5:32.2:35.2 wt % respectively at 350°C for 2...

A little over a decade ago, Waldichuk (1990) reviewed the state of industrial and domestic pollution of the North Pacific and concluded that interfaces (e.g., air-water, water-sediment, shorelines) and coastal areas, especially those surrounded by dense population and industry, were most at risk. His list of critical contaminants – hydrocarbons and polynuclear aromatic hydrocarbons (PAHs), orga...

On Zugspitze (2670 m a.s.l.), Alps, higher concentrations were observed during a winter than during a summer measurement campaign of PAHs, chlorobenzenes (43.6 vs. 2.0 pg m(-3)) and DDTs (3.7 vs. 1.2 pg m(-3)), while hexachlorocyclohexanes and PCBs were found at similar levels. The PCB, HCH and DDT levels are among the lowest ever reported from outside the Arctic. Mostly lower levels were found...

hydrocarbons (PAHs) in coastal marine sediments: case studies in Cotonou (Benin) and Aquitaine (France) areas. Marine Pollution Bulletin 40, 387–396. Steinhauer, M.S., Boehm, P.D., 1992. The composition and distribution of saturated and aromatic hydrocarbons in near shore sediments, river sediments, and coastal peat of Alaskan Beaufort Sea: implications for detecting anthropogenic hydrocarbon i...

Functionalizing of single molecules on surfaces has manifested great potential for bottom-up construction of complex devices on a molecular scale. We discuss the growth mechanism for the initial layers of polycyclic aromatic hydrocarbons on metal surfaces and we review our recent progress on molecular machines, and present a molecular rotor with a fixed off-center axis formed by chemical bondin...

We report the results of a broadband rotational spectroscopic study of corannulene, C20H10, all of its singly substituted 13C isotopologues, and a complex of corannulene with one molecule of water. Corannulene is a polycyclic aromatic hydrocarbon (PAH) with a curved structure that results in a large dipole moment. Observation of 13C isotopic species in natural abundance allowed us to precisely ...