نتایج جستجو برای: atomic charge
تعداد نتایج: 228101 فیلتر نتایج به سال:
Chemical hardness (), absolute electronegativity (), and electrophilicity () have importantapplications in inorganic chemistry. These concepts are defined quantitatively as � � �� � ����,� � �� � ����, � � ������Where I is the ionization energy and A is the electron affinity. In thisstudy, graphical method was used to see the relation of electron configuration with chemicalhardness, absolute el...
A strong interplay between charge, lattice, orbital and spin degrees of freedom exists in transition-metal oxides yielding the emergence of a large spectrum of functionalities such as hightemperature superconductivity, metal/insulator transition, multiferroicity, thermoelectricity... More specifically, mixed valence states of 3d elements issue as a driving force in such interplay. In addition, ...
We use the Newns-Anderson Hamiltonian to describe many-body electronic processes that occur when hyperthermal alkali atoms scatter off metallic surfaces. Following Brako and Newns, we expand the electronic many-body wavefunction in the number of particle-hole pairs (we keep terms up to and including a single particle-hole pair). We extend their earlier work by including level crossings, excited...
ar X iv : p hy si cs / 0 31 01 23 v 2 2 7 O ct 2 00 3 Small rare gas clusters in soft X - ray pulses
We develop a microscopic model for the interaction of small rare gas clusters with soft X-ray radiation. It is shown that, while the overall charging of the clusters is rather low, unexpectedly high atomic charge states can arise due to charge imbalances inside the cluster. The mechanism does not require unusually high absorption rates, and the heating can be described by standard inverse brems...
Poor screening of the long-range Coulomb interaction in one-dimensional carbon nanotubes results in a peculiar picture of contact phenomena. Being brought to a contact with a metal, conducting nanotube accumulates electric charge whose density decays slowly with the distance from the contact. This should be contrasted to a conventional metal-metal contact where the charge density decreases expo...
Contributions from the Breit interaction in atomic structure calculations account for 1.3sigma of the previously reported 2. 5sigma deviation from the standard model in the 133Cs weak charge [S. C. Bennett and C. E. Wieman, Phys. Rev. Lett. 82, 2484 (1999)]. The updated corrections for the neutron distribution reduce the discrepancy further to 1.0sigma. The updated value of the weak charge is Q...
We have directly observed reversal of the polarity of charged surfaces in water upon the addition of trivalent and quadrivalent ions using atomic force microscopy. The bulk concentration of multivalent ions at which charge inversion reversibly occurs depends only very weakly on the chemical composition, surface structure, size, and lipophilicity of the ions, but is very sensitive to their valen...
We have performed precision atomic spectroscopy of trapped radioactive Be isotopes aiming at studies of the charge and magnetization radii of these nuclei especially for a single-neutron halo nucleus Be. Some experimental results and the status of the analysis are discussed. PACS. 21.10.Gv Nucleon distributions and halo features – 21.10.Ft Charge distribution – 31.30.Gs Hyperfine interactions a...
Two-dimensional (2D) molybdenum disulphide (MoS2) atomic layers have a strong potential to be used as 2D electronic sensor components. However, intrinsic synthesis challenges have made this task difficult. In addition, the detection mechanisms for gas molecules are not fully understood. Here, we report a high-performance gas sensor constructed using atomic-layered MoS2 synthesised by chemical v...
We have measured shot noise in aluminum atomic point contacts containing a small number of conduction channels of known transmissions. In the normal state, we find that the noise power is reduced from its Poissonian value and reaches the partition limit, as calculated from the transmissions. In the superconducting state, the noise reveals the large effective charge associated with each elementa...
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