Structure, morphology and composition of two Pd/Ga2O3 methanol steam reforming catalysts were correlated with the associated activity and selectivity changes in the methanol steam reforming reaction and linked to studies on pure Ga2O3 supports. For both systems, that are, a Pd/Ga2O3 thin film model catalyst and a powder-supported Pd catalyst, we identified a temperature range in which the reduc...

Pd particles supported on SnO2 and GeO2 have been structurally investigated by X-ray diffraction, (High-Resolution) transmission and scanning electron microscopy after different reductive treatments to monitor the eventual formation of bimetallic phases and catalytically tested in methanol dehydrogenation/reforming. For both oxides this included a thin film sample with well-defined Pd particles...

In this study, the structures, the IR spectroscopy, and the electronic properties of AunCum (n+m≤5) bimetallic clusters were studied and compared with those of pure gold and copper clusters using the generalized gradient approximation (GGA) and exchange correlation density functional theory (DFT). The study of an O2-AunCum system is important to identify the promotion effects of each of the two...

Wire electric discharge machine (WEDM) is spark erosion in unconventional machining technique to cut hard and the conductive material with a wire as an electrode. The blanking die material SKD 11 is a high carbon and high chromium tool steel with high hardness and high wearing resistance property. This tool steel has broad application in press tools and dies making industries. In this research ...

An efficient synthesis of spiroaminals over fused aminals has been successfully developed by bimetallic Au/Sc catalysis by using TMS as a traceless controlling group.

UV irradiation of TiO(2) loaded with bimetallic Pd-Pt alloy particles promotes highly efficient dehalogenation of organic halides with alcohol as a hydrogen source.

Atomic-level understanding of the structural transformations of multimetallic nanoparticles (NPs) triggered by external stimuli is of vital importance to the enhancement of our capabilities to precisely fine-tailor the key structural parameters and thereby to fine-tune the catalytic properties of the NPs. In this work, I firstly show that Au-Cu bimetallic NPs demonstrate stoichiometry-dependent...

introduction: any decrease in friction between orthodontic wire and bracket can accelerate tooth movement in the sliding technique and result in better control of anchorage. the present study was carried out to decrease this friction by coating of zinc oxide nanoparticles (zno) on orthodontic wires and porcelain brackets. materials and methods: in this in vitro study, a combination of 120 0.019...

Nanometric Carbid Silicon (SiC) supported monometallic and bimetallic catalysts containing Fe, Co, Ni transition metals were prepared by wet impregnation method. Multiwall carbon nanotubes (MWCNTs) were synthesized over the prepared catalysts from catalytic decomposition of acetylene at 850°C by thermal chemical vapor deposition (TCVD) technique. The synthesized nanomaterials (catalysts and CNT...

Polynuclear transition metal complexes, which are embedded in the active sites of many metalloenzymes, are responsible for effecting a diverse array of oxidation reactions in nature. The range of chemical transformations remains unparalleled in the laboratory. With few noteworthy exceptions, chemists have primarily focused on mononuclear transition metal complexes in developing homogeneous cata...