A novel type of acetylcholine electrochemical biosensor was successfully fabricated by dropping beta-cyclodextrin solution, acetylcholinesterase solution and Nafion-methanol solution to the homemade nano-porous pseudo carbon paste electrode (nano-PPCPE) as working electrode, and then the electrochemical behavior of the as-prepared biosensor was studied through the acetylthiocholine iodide (ATCh...

Carbon nanotubes are of great interest due to their high surface area and rich edge sites, which are favorable for wide applications. Here, a simple and efficient routine is presented by decoration of multi-wall carbon nanotube (MWCNT) with nickel oxide (NiO) nanoparticles.The morphologies of NiO-MWCNT  were  investigated  by  using scanning  electron  microscope  (SEM)  and energydispersive X-...

Gold is determined in aqueous gold-containing drug solutions, 8 X 108 to 1 X 10 mol/liter, and in such drugs in serum, 2 X 106 to 1 X 10 mol/ liter, by electrodeposition onto a carbon paste electrode at -0.3 V vs. a saturated calomel electrode and subsequent stripping at constant current. Aqueous solutions are prepared for electrodeposition with a ceric perchlorate-hydrogen peroxide treatment. ...

The oxidation of ketoconazole on a bare carbon paste electrode was studied voltammetrically. The results indicated that the process is irreversible and controlled by an adsorption-extraction process which allows the accumulation of the drug at the electrode surface. After the optimization of solution pH, accumulation variables and instrumental parameters, sensitive differential pulse and linear...

A modified electrode was prepared by modification of the carbon paste electrode (CPE) with graphene nano-sheets. The fabricated modified electrode exhibited an electrocatalytic activity toward gallic acid (GA) oxidation because of good conductivity, low electron transfer resistance and catalytic effect. The graphene modified CPE had a lower overvoltage and enhanced electrical current respect to...

a carbon ionic liquid electrode (cile) modified with tio2-fe nanoparticles was constructed by incorporating tio2-fe nanoparticles into the paste matrix. under the optimized experimental conditions, using differential pulse voltammetry (dpv), the oxidation of thiocyanate and oxalate were occurred at potentials of 0.740 v and 1.010 v, respectively, at the surface of the modified electrode. observi...

A bienzymatic biosensor incorporating a mediator has been developed in order to achieve a fast and selective detection of glucose in a flow injection system. The working electrode is based on a carbon paste matrix bulk modified with glucose oxidase (GOD) and horseradish peroxidase (HRP) as well as with ferrocene acting as an electron transfer mediator between the electrode and HRP. The proximit...

A sensitive and convenient electrochemical method was developed for the simultaneous determination of the isomers of Ponceau 4R and Amaranth by an expanded graphite paste electrode (EGPE). The EGPE was prepared by mixing EG with solid paraffin. Compared with flake graphite paste and carbon paste electrodes, the EGPE showed higher electrocatalytic activity towards the oxidization of Ponceau 4R a...

Using two nano-porous pseudo carbon paste electrodes (Nano-PPCPEs) as the working electrodes, a saturated calomel electrode as the reference electrode, and a Pt electrode as the counter electrode to form a four-electrode system, a novel type of glutamate-acetylcholine electrochemical biosensor array was successfully fabricated. It was shown that the biosensor array displayed a high selectivity ...

Electroanalytical parameters of different graphitic carbon-based electrode materials were compared to select the best one for the pantoprazole electroanalysis. Such parameters include sensitivity, repeatability, residual background current, and signal-tobackground current ratio of the analytical response and such electrodes include conventional carbon-based electrodes such as glassy carbon (GC)...