γ-Alumina is widely used as an oxide support in catalysis, and palladium nanoparticles supported by alumina represent one of the most frequently used dispersed metals. The surface sites of the catalysts are often probed via FTIR spectroscopy upon CO adsorption, which may result in the formation of surface carbonate species. We have examined this process in detail utilizing FTIR to monitor carbo...

The present study focuses on facies analysis and the reservoir characteristics of the Asmari Formation in the Aghajari oilfield (located in the Zagros fold-thrust belt, southwest Iran), and how they are linked to depositional environments and reservoir characteristics. This formation consists of about 380 m carbonates with some siliciclastic intercalations. Based on the integration of 1200 m of...

Cyanobacteria are thought to play a key role in carbonate formation due to their metabolic activity, but other organisms carrying out oxygenic photosynthesis (photosynthetic eukaryotes) or other metabolisms (e.g., anoxygenic photosynthesis, sulfate reduction), may also contribute to carbonate formation. To obtain more quantitative information than that provided by more classical PCR-dependent m...

A mild and efficient one-pot three-component and environmentally benign approach for the synthesis of a wide range of hydantoin annulated derivatives has been described. A multi-component reaction between a carbonyl compounds (ketone or aldehyde), potassium cyanide and ammonium carbonate (as cyanating agent and amine source, respectively leads to the formation of hydantoins. The proposed optimi...

Fish otoliths, biominerals composed of calcium carbonate with a small amount of organic matrix, are involved in the functioning of the inner ear. Starmaker (Stm) from zebrafish (Danio rerio) was the first protein found to be capable of controlling the formation of otoliths. Recently, a gene was identified encoding the Starmaker-like (Stm-l) protein from medaka (Oryzias latipes), a putative homo...

A multi-nuclear solid-state NMR approach is employed to investigate the lithium-air battery, to monitor the evolution of the electrochemical products formed during cycling, and to gain insight into processes affecting capacity fading. While lithium peroxide is identified by 17O solid state NMR (ssNMR) as the predominant product in the first discharge in 1,2-dimethoxyethane (DME) based electroly...

The trace fossil assemblages from the Unit 2 of Deh-Sufiyan Formation are described for the first time from The Central Alborz Range of northern Iran,  improving the record of the assemblages in the Cambrian of the Middle East. Twenty-one ichnogenera have been identified in the Deh-Sufiyan Formation, namely Arenicolites, Bergaueria, Chondrites, Circulichnus, Cruziana, Diplichnites, Didymaulichnu...

Paleoelevation reconstruction using stable isotopes, although a relatively new science, is making a signifi cant contribution to our understanding of the recent growth of the world’s major orogens. In this review we examine the use of both light stable isotopes of oxygen and the new “clumped-isotope” (Δ47) carbonate thermometer in carbonates from soils. Globally, the oxygen isotopic composition...

OBJECTIVE The objective of this study was to histologically and histomorphometrically evaluate the efficacy of the new formulations of eggshell-derived calcium carbonate in rats. STUDY DESIGN The study was conducted on 30 adult male rats. Four standardized and circular intrabony defects were created in the both maxilla and mandibula of each animal. Three different graft materials were prepare...

a mild and efficient one-pot three-component and environmentally benign approach for the synthesis of a wide range of hydantoin annulated derivatives has been described. a multi-component reaction between a carbonyl compounds (ketone or aldehyde), potassium cyanide and ammonium carbonate (as cyanating agent and amine source, respectively leads to the formation of hydantoins. the proposed optimi...