We have recently synthesized [Ni (MAP) ] complex [H-MAP= 2- (methylamino) pyridine]. 2- (Methy1amino)pyridine reacts with MeLi in THF and generates the lithium salt (Li-MAP). Further reaction of NiCl with two equivalent of this ligand in THF leads to the formation of a dark red solution. Analytical data, molecular weight, and magnetic susceptibility of this complex confirm the formula [N...

This study investigates the crystal structure, physicochemical properties, and pharmacokinetic profile of Ethyl 2-amino-6-methyl-4,5,6,7-tetrahydrothieno[2,3-c]pyridine-3-carboxylate (EAMT) as a potential therapeutic agent. The structure was analyzed using Hirshfeld surface analysis in conjunction with quantum theory atoms molecules (QT-AIM). Non-covalent interactions were evaluated through red...

This work reports, immobilization the Cobaloxime [Co (DH) Cl;DH,dimethylglyoximato)] onto the MCM- .The surface of MCM- was initially functionalized with -aminopropyltrimethoxysilane and -pyridine. For the electrostatic immobilization this was reacted with Cobaloxime and immobilization was achieved by an electrostatic interaction between the Co Cobaloxime and the N of the pyridine and NH amine....

nicotine-based ionic liquid has been used as a green catalyst for pyridine-catalyzed huisgen reaction. it promoted addition of dimethylacetylenedicarboxylate to aldehydes or n-tosyl imines leading to efficient synthesis of 2-benzoylfumarates and 1-azadienes respectively under pyridine free odorless ionic liquid conditions. the improved results were obtained in terms of enhanced yields, with min...