a series of transition metal complexes with two thiosemicarbazide schiff bases, 1-(4-dimethylaminobenzyl- idene)thiosemicarbazide (abtsc) and 1-(2-pyridincarboxyl-idene) thiosemicarbazide (tcts) were synthesized with co(ii), ni(ii), zn(ii), cd(ii) and ag(i) salts (chloride and acetate). these complexes were characterized by different methods including proton nuclear magnetic resonance (1hnmr), ...

an atom-efficient, eco-friendly, solvent-free, high yielding, multicomponent green strategy to synthesize triazolo[1,2-a]indazole-triones derivatives by the one-pot condensation of aldehyde, dimedone, and phenyl urazole is presented. a series of different substituted aromatic aldehydes including either electron-withdrawing or electron-donating groups used in this reaction participated well and ...

the perovskite-structured la2cuo4 nanoparticles have been synthesized via an ultrasonic-assisted co-precipitation route using octanoic acid as organic surfactant, and the phase composition, morphology, lattice parameters and size of nanoparticles are characterized through fourier transform infrared spectroscopy, x-ray diffraction, scanning electron microscopy and transmission electron microscop...

Production of a biocompatible hyperpolarized bolus for signal amplification by reversible exchange (SABRE) could open the door to simple clinical diagnosis via magnetic resonance imaging. Essential to successful progression to preclinical/clinical applications is the determination of the toxicology profile of the SABRE reaction mixture. Herein, we exemplify the cytotoxicity of the SABRE approac...

Aggregation in heat-treated Nafion ionomer dispersion and 117 membrane are investigated by 1H and 19F Nuclear Magnetic Resonance (NMR) spectra, spin-lattice relaxation time, and self-diffusion coefficient measurements. Results demonstrate that heat-treatment affects the average Nafion particle size in aqueous dispersions. Measurements on heat-treated Nafion 117 membrane show changes in the 1H i...

A Simple and environmentally friendly  procedure for the one-pot multi-component synthesis of 3,4-dihydropyrimidin-2(1H)-one derivatives has been developed by one pot three component reaction of various aldehydes, β-dicarbonyl, and urea in the presence of catalytic amount of tris (trihexyltetradecylphosphonium) gadolinium hexachloride [P6,6,6,14]3 [GdCl6] as a solid acid catalyst without any ad...

Caffeine loaded magnetic nanoparticle was successfully synthesized and were characterized by Fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray analysis (EDX), thermo gravimetric analysis (TGA), differential thermal analysis (DTA) and vibrating sample magnetometer (VSM). The resulting nanocom...

1, 4-Diazabicyclo [2.2.2] octane (DABCO) was employed as a catalyst for one-pot synthesis of pyrano[2,3-d] pyrimidinone derivatives and MWNT- pyrimidinones from condensation reactions of aromatic aldehydes, malononitrile and thiobarbituric acid and MWNT-COCl . This method delivers the advantages of a simple method, environment friendly procedure, mild reaction conditions and high returns. The m...

We control quantum fluctuations to create the ground state magnetic phases of a classical Ising model with a tunable longitudinal magnetic field using a system of 6 to 10 atomic ion spins. Because of the long-range Ising interactions, the various ground state spin configurations are separated by multiple first-order phase transitions, which in our zero temperature system cannot be driven by the...

In order to screen one suitable catalyst for magnetically stabilized fluidized bed (MSFB) reactor in the process of oxidative carbonylation of phenol to diphenyl carbonate (DPC), Pd/MFe2O4 catalysts were chosen, then prepared and characterized by XRD, H2-TPR, XPS and vibrating sample magnetometer (VSM). Compared to the other metal ion doped spinel ferrite catalysts, the catalytic activity of Pd...