C(2)H(4)/CO/H(2) reaction is investigated on Rh/SiO(2) model catalyst surfaces. Kinetic reactivity and infrared spectroscopic measurements are investigated as a function of Rh particle size under near atmospheric reaction conditions. Results show that propionaldehyde turnover frequency (TOF) (CO insertion pathway) exhibits a maximum activity near = 2.5 nm. Polarization modulation infrare...

Microstructural characteristics of various real Cu/ZnO/Al2O3 catalysts for methanol steam reforming (MSR) were investigated by in situ X-ray diffraction (XRD), in situ X-ray absorption spectroscopy (XAS), temperature programmed reduction (TPR) and electron microscopy (TEM). Structure–activity correlations of binary Cu/ZnO model catalysts were compared to microstructural properties of the ternar...

Correlation between traffic density and particle size distribution in a street canyon and the dependence on wind direction J. Voigtländer, T. Tuch, W. Birmili, and A. Wiedensohler Leibniz Institute for Tropospheric Research, Leipzig, Germany UFZ Center for Environmental Research, Department of Human Exposure Research and Epidemiology, Leipzig, Germany Received: 14 February 2006 – Accepted: 6 Ma...

We show that disorder-induced interaction between guided modes and a flat band of low-Q radiating modes in planar arrays of dielectric particles can lead to frequency-selective omni-directional scattering of light. This phenomenon is numerically observed in planar arrays consisting of periodically arranged dielectric particles with small randomness in particle sizes. The flat band of low-Q radi...

Conventional supported metal catalysts are metal nanoparticles deposited on high surface area oxide supports with a poorly defined metal-support interface. Typically, the traditionally prepared Pt/ceria catalyzes both methanation (H2/CO to CH4) and water-gas shift (CO/H2O to CO2/H2) reactions. By using simple nanochemistry techniques, we show for the first time that Pt or PtAu metal can be crea...

Due to their unique structure and physical properties and numerous potential applications, carbon nanotubes have been extensively studied recently and are expected to attract more attention in the future.1 Morphology control of carbon nanotubes represents one of the most explored directions. Except for the normal linear structure, nanotubes with morphologies of ring,2 rocket,2 branch,3 cone,4 b...

In slurry bubble column reactors, catalyst particles may adhere to gas bubbles. Thus, mass transfer limited reactions can be significantly improved either by increasing G-L mass transfer coefficient kL or specific surface area a. The scope of this work is to study the influence of model parameters on coalescence and G-L mass transfer, in order to develop new rules for design and scale-up of slu...

the mixed metal nanocomposite mgo∙al2o3∙zno has been prepared by coprecipitation method. the product was characterized by xrd. the average particle size was found to be 34.89 nm from xrd data. sem and sem-eds were studied for evaluating surface morphology and elemental composition. the ftir spectrum of prepared mixed metal nanocomposites mgo∙al2o3∙zno and mgo∙al2o3∙zno-curcumin were studied. th...

In this study, the effects of limited hydrolysis and/or high-pressure homogenization (HPH) treatment in acid conditions on the functional properties of oyster protein isolates (OPI) were studied. Protein solubility, surface hydrophobicity, particle size distribution, zeta potential, foaming, and emulsifying properties were evaluated. The results showed that acid treatment led to the dissociatio...

The accuracy and practicality of particle size distribution analysis for rapid screening of urine specimens are assessed. Six hundred urines were subjected simultaneously to routine bacteriological examinations and particle size distribution analysis using a Coulter Counter (ZBI) linked to a C1000 Channelyzer. There was complete agreement in the results of 593 (98.8%) specimens. Characteristic ...