Three new thiophenyl bridged triarylamine-donor based dyes with pyridyl anchoring groups and indolium acceptors have been synthesized studied as sensitizers for the p-type dye-sensitized solar cell (p-DSSC). Compared to known dicyano pyridinium same triarylamine cores, these broadened red-shifted UV–vis absorption spectra, high extinction coefficients extending beyond 700 nm. TD-DFT calculation...