نتایج جستجو برای: ceo2 سل
تعداد نتایج: 6625 فیلتر نتایج به سال:
در این پژوهش نانوساختارهای لانتانیم هیدروکسید ((la(oh)3 و سریم اکسید (ceo2) به کمک روش هیدروترمال با استفاده از لانتانیم کلرید هفت آبه، آمونیوم سریم نیترات، اتیلن دی آمین و هیدرازین به عنوان پیش ماده تهیه شدند. اثر پارامترهای تجربی مختلفی از قبیل دمای واکنش، زمان واکنش، نسبت مولی واکنش دهنده ها بر اندازه و شکل محصولات نهایی مورد بررسی قرار گرفت. یافته های ما نشان داد که غلظت اتیلن دی آمین و زما...
The correlation between the occurrence state of surface Pd species Pd/CeO2 for lean CH4 combustion is investigated. Herein, by using a reduction-deposition method, we have synthesized highly active 0.5% PdO/CeO2-RE catalyst, in which nanoparticles are evenly dispersed on CeO2 nanorods CeO2-R. Based comprehensive characterization, revealed that uniformly with particle size distribution 2.3 ± 0.6...
Introduction Soot particles and NOx are the main pollutants from diesel engines. Good alternatives to abate these contaminants are the use of catalytic filters, which burn the soot particles, and NOx traps which adsorb the NOx during normal operation and released them during reduction cycles [1]. We recently studied BaK/CeO2 catalysts for this application[2]. Barium plays the role of NOx adsorb...
Cerium dioxide nanoparticles (CeO2 NPs) are increasingly being used as a catalyst in the automotive industry. Consequently, increasing amounts of CeO2 NPs are expected to enter the environment where their fate in and potential impacts are unknown. In this paper we describe the fate and effects of CeO2 NPs of three different sizes (14, 20, and 29 nm) in aquatic toxicity tests. In each standard t...
A surfactant-free route was successfully established to synthesize CeO2 single-crystalline nanowires using H2O2 as oxidizer and template agent.
The interaction and mechanism for CO oxidation on a Ru-modified CeO2 surface have been investigated by using periodic density functional theory calculations corrected with the on-site Coulomb interaction via a Hubbard term (DFT + U). Our calculations showed that (i) the Ru dopant facilitates oxygen vacancy formation, while the Ru adatoms may suppress oxygen vacancy formation. (ii) Physisorbed C...
We reported Ce and its oxide-modified TiO2 nanotube arrays (TNTs) and their semiconductor properties. The TNTs were prepared by anodic oxidation on pure Ti and investigated by electrochemical photocurrent response analysis. Then, the TNT electrodes were deposited of Ce by cathodic reduction of Ce(NO3)3 6H2O. After deposition, the TNT electrodes were fabricated by anodic oxidation at E = 1.0 V(S...
This article reports the green fabrication of cerium oxide nanoparticles (CeO2 NPs) using Olea europaea leaf extract and their applications as effective antimicrobial agents. O. europaea leaf extract functions as a chelating agent for reduction of cerium nitrate. The resulting CeO2 NPs exhibit pure single-face cubic structure, which is examined by X-ray diffraction, with a uniform spherical sha...
Diffusion processes and reactions of H at stoichiometric and reduced CeO2(111) surfaces have been studied by using density functional theory calculations corrected by on-site Coulomb interactions (DFT + U). Oxygen vacancies on the surface are determined to be able to significantly affect the behavior of H by modifying the charge of surface lattice O through the occurrence of Ce(3+). It has been...
In this work, nanostructured CeO2 microspheres with high surface area and mesoporosity were prepared by the coprecipitation method, in absence of a template. The reaction between cerium nitrate and concentrated formic acid produced cerium formate, at room temperature. Further, calcination at 300 °C yielded single-phase CeO2 microspheres, with a diameter in the range 0.5-2.6 μm, the surface of t...
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