in this paper, the adsorption of cerium on modified mesoporous aluminosilicate (with si/al mole ratio of 10) was studied. the effects of ph, contact time, initial concentration of cerium on adsorption of cerium were investigated. the adsorption capacity was high in the ph range of 4-8 and decreases with decreasing of the ph value. the langmuir and freundlich isotherms were applied to represent ...

Cerium-rich metal oxide materials have recently emerged as promising candidates for the photocatalytic oxygen evolution reaction (OER). In this article, we report the synthesis of ordered mesoporous CuO/CeO₂ composite frameworks with different contents of copper(II) oxide and demonstrate their activity for photocatalytic O₂ production via UV-Vis light-driven oxidation of water. Mesoporous CuO/C...

The excitement of nano-test-tube chemistry in a single-walled carbon nanotube is exemplified in our study on electron doping in carbon nanotubes. Electron doping through the 1D van Hove singularity of single-walled carbon nanotubes is realized via a chemical reaction of an encapsulated organocerium compound, CeCp3. The decomposition of CeCp3 inside the carbon nanotubes increases the doping leve...

We report the presence of a correlation between the bulk and interfacial properties of electrostatic coacervate complexes. Complexes were obtained by co-assembly between cationic-neutral diblocks and oppositely charged surfactant micelles or 7 nm cerium oxide nanoparticles. Light scattering and reflectometry measurements revealed that the hybrid nanoparticle aggregates were more stable through ...

We present a comprehensive thermodynamic and kinetic analysis of the suitability of cerium oxide (ceria) for thermochemical fuel production. Both portions of the two-step cycle, (i) oxygen release from the oxide at 1773 and 1873 K under inert atmosphere, and (ii) hydrogen release upon hydrolysis at 1073 K, are examined theoretically as well as experimentally. We observe gravimetric fuel product...

Ceriuii dioxide doped with y 3 + ions, which is of interest for its ionic conductivity, is here studied by anelastic ~~~ethods. The internal friction peaks observed are analyzed intc peals A , B, C (with Hr = 0.64, 0.71 and 0.78 eV, respectively). Peak A, present at low y3+ concentrations is established to be due to a W pair (V = oxygen-ion vacancy), which is a charged defect conpensated by an ...

A new catalyst comprising cerium and silver ion-exchanged ZSM-5 zeolite is reported in this paper, for the reduction of nitric oxide by methane in the presence of excess oxygen. The bi-cation exchanged Ce-Ag-ZSM-5 catalyst was very active for this reaction, while either Ce-ZSM-5 or Ag-ZSM-5 alone showed low activity. The presence of oxygen in the feed gas mixture enhanced the activity of the ca...

An experimental investigation is carried out to establish the performance and emission characteristics of a compression ignition engine while using cerium oxide nanoparticles as additive in neat diesel and diesel-biodiesel-ethanol blends. In the first phase of the experiments, stability of neat diesel and diesel-biodiesel-ethanol fuel blends with the addition of cerium oxide nanoparticles are a...

Intra-granular Acicular Ferrite (IAF), as one of the most well-known desirable microstructure of ferrite with a chaotic crystallographic orientation, can not only refine the microstructure and retard the propagation of cleavage crack but also provide excellent combination of strength and toughness in steel. The effect of adding cerium on microstructure and controlling proper cerium-based inclus...

We report the synthesis of cerium oxide, cobalt oxide, mixed cerium, and cobalt oxides and a Ce-Co/Al₂O₃ membrane, which are employed as catalysts for the catalytic wet oxidation (CWO) reaction process and the removal of formaldehyde from industrial effluents. Formaldehyde is present in numerous waste streams from the chemical industry in a concentration low enough to make its recovery not econ...