In this paper, the adsorption of cerium on modified Mesoporous aluminosilicate (with Si/Al mole ratio of 10) was studied. The effects of pH, contact time, initial concentration of cerium on adsorption of cerium were investigated. The adsorption capacity was high in the pH range of 4-8 and decreases with decreasing of the pH value. The Langmuir and Freundlich isotherms were applied to represent ...

Transparent bubble free phosphate glasses with composition 50P2O5-10Al2O3-20CaO-(20-x)Na2O-xCeO2 (x varying from 0 to 4 mol %) have been prepared using melt quenching technique. The amorphous nature of the prepared glass samples has been confirmed from XRD spectra. The optical absorption coefficient has been determined from the UVvisible absorption spectra. The prepared glass samples have been ...

The ultra-precision diamond cutting process exhibits strong size effects due to the ultra-small depth of cut that is comparable with the cutting edge radius. In the present work, we elucidate the underlying machining mechanisms of single crystal cerium under diamond cutting by means of molecular dynamics simulations, with an emphasis on the evaluation of the effect of depth of cut on the cuttin...

A simple, sensitive and precise green high-performance liquid chromatographic method including on-line pre-column oxidation combined by column switching with a short Hypersil ODS analytical column (100 mm × 4.0 mm i.d.) for enrichment and separation was developed and validated to determine low levels of methotrexate (MTX). The method was based on oxidative cleavage of MTX into highly fluorescen...

Nanoparticles of palladium-doped cerium oxide (Pd–CeO2) have been prepared by aqueous co-precipitation resulting in a single phase cubic structure after calcination according to X-ray diffraction (XRD). Inhomogeneous strain, calculated using the Williamson–Hall method, was found to increase with palladium content, and the lattice contracts slightly, relative to nano-cerium oxide, as palladium c...

The effect of nanomaterials on biota under realistic environmental conditions is an important question. However, there is still a lack of knowledge on how different illumination conditions alter the toxicity of some photocatalytic nanomaterials. We have investigated how environmentally relevant UV-A exposure (intensity 8.50 ± 0.61 W/m(2), exposure dose 9.0J/cm(2)) affected the toxicity of ceriu...

Primary aquo species of tetravalent cerium (Ce(IV)) in perchloric acid has been identified as a single oxo-bridging dinuclear complex, not a mononuclear one, by extended X-ray absorption fine structure (EXAFS) spectroscopy combined with density functional theory (DFT) calculations.

A new simple, sensitive and precise green analytical procedure using an automated packed-reactor derivatization technique coupled with on-line solid-phase enrichment (SPEn) has been developed and evaluated to determine trace levels of methotrexate (MTX). The method was based on injection of MTX into a flowing stream of phosphate buffer (0.04 M, pH 3.4), carried through the packed oxidant reacto...