Biomass offers a renewable carbon source that could be utilized as a raw material in the chemicals industry. A potential route for the conversion of biomass feedstock’s into industrial chemicals is through the catalytic conversion of biomass sugars (glucose) to furan based compounds through an aqueous reforming process. However, to accommodate the transport of these bulky sugars within the cata...

The catalyst Pt(1 wt %)/Ce(0.6)Zr(0.4)O(2) is studied by CO-temperature programmed reduction (CO-TPR), isothermal oxygen storage complete capacity (OSCC), X-ray absorption spectroscopy (XAS) at the Pt L(III) edge, and in situ X-ray diffraction (in situ XRD), with the aim of elucidating the role of supported metal in CO oxidation by ceria-based three-way catalysts (TWC). The redox behavior of Pt...

This review introduces concepts and background from the ceramics engineering literature regarding metastable zirconia ceramics to establish a context for understanding current and emerging zirconia-based dental ceramics.

The hydrogen solubility in zirconia (yttria stabilized zirconia, YSZ) using a tritium imaging plate (IP) technique has been measured in a temperature region ranging from 673K to 973K. The tritium distribution in the zirconia specimens was nearly uniform suggesting an equilibrated dissolution. The hydrogen solubility in specimens were rather low (around ppm or below) and showed Arrhenius type te...

BACKGROUND Glass-ionomer cements perform a protective effect on the dentin-pulp complex considering the F ions release and chemical bonding to the dental structures. On the other hand, those materials have poor physic-mechanical properties in comparison with the restorative resin composite. The main aim of this work was to evaluate the influence of zirconia and/or alumina fillers on the microst...

OBJECTIVE This study assessed how changing the Zirconia (Zr) substructure affected the color samples after they have been overlaid by the same shade of veneering ceramic. MATERIALS AND METHODS Three commercial Zr materials were tested in this study: Prettau(®) Zirconia (ZirKonZahn, Italy), Cercon (Dentsply, Germany) and InCoris ZI (Sirona, Germany). For each system, 15 disk-shaped specimens (...

STATEMENT OF PROBLEM Successful long-term bonding to zirconia ceramic remains a challenge, requiring special cements and surface roughening by airborne-particle abrasion, which might negatively affect the ceramic. PURPOSE The purpose of this study was to evaluate the shear bond strength (SBS) of composite resin cylinders to a modified zirconia surface using different luting techniques after t...

For fixed dentures, new generations of zirconia with diverse characteristics and design choices are significant interest. Although in vitro studies finite element analysis (FEA) have been published, comprehension various methods material testing remains insufficient. Young’s modulus Poisson’s ratio the desired materials must be available for investigators to validate FEA investigations that acc...

the aim of this study was to determine the effect of trenched zirconia bar on the von mises stress distribution of ips -empress ii core ceramics.the three-dimensional model including a three-unit bridge from the second premolar to the second molar was designed. the model was reinforced with zirconia bar (zb), zirconia bar with vertical trench (vzb) and zirconia bar with horizontal trench (hzb) ...

STATEMENT OF PROBLEM Zirconia-based restorations have the common technical complication of delamination, or porcelain chipping, from the zirconia core. Thus the shear bond strength between the zirconia core and the veneering porcelain requires investigation in order to facilitate the material's clinical use. PURPOSE The purpose of this study was to evaluate the bonding strength of the porcela...